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  2. Irreducible representation - Wikipedia

    en.wikipedia.org/wiki/Irreducible_representation

    Every finite-dimensional unitary representation on a Hilbert space is the direct sum of irreducible representations. Irreducible representations are always indecomposable (i.e. cannot be decomposed further into a direct sum of representations), but the converse may not hold, e.g. the two-dimensional representation of the real numbers acting by ...

  3. List of character tables for chemically important 3D point groups

    en.wikipedia.org/wiki/List_of_character_tables...

    The body of the tables contain the characters in the respective irreducible representations for each respective symmetry operation, or set of symmetry operations. The symbol i used in the body of the table denotes the imaginary unit: i 2 = −1. Used in a column heading, it denotes the operation of inversion.

  4. Wigner D-matrix - Wikipedia

    en.wikipedia.org/wiki/Wigner_D-matrix

    The Wigner D-matrix is a unitary matrix in an irreducible representation of the groups SU(2) and SO(3). It was introduced in 1927 by Eugene Wigner, and plays a fundamental role in the quantum mechanical theory of angular momentum. The complex conjugate of the D-matrix is an eigenfunction of the Hamiltonian of spherical and symmetric rigid rotors.

  5. Representation theory of finite groups - Wikipedia

    en.wikipedia.org/wiki/Representation_theory_of...

    The representation is called an irreducible representation, if these two are the only subrepresentations. Some authors also call these representations simple, given that they are precisely the simple modules over the group algebra []. Schur's lemma puts a strong constraint on maps between irreducible representations.

  6. Molecular symmetry - Wikipedia

    en.wikipedia.org/wiki/Molecular_symmetry

    The irreducible representation for the C-O stretching vibration is A 1g + E g + T 1u. Of these, only T 1u is IR active. B 2 H 6 has D 2h molecular symmetry. The terminal B-H stretching vibrations which are active in IR are B 2u and B 3u. Diborane. Fac-Mo(CO) 3 (CH 3 CH 2 CN) 3, has C 3v geometry. The irreducible representation for the C-O ...

  7. Wigner's classification - Wikipedia

    en.wikipedia.org/wiki/Wigner's_classification

    This is the double cover of SE(2) (see projective representation). We have two cases, one where irreps are described by an integral multiple of ⁠ 1 / 2 ⁠ called the helicity, and the other called the "continuous spin" representation. For the third case The only finite-dimensional unitary solution is the trivial representation called the vacuum.

  8. Representation theory - Wikipedia

    en.wikipedia.org/wiki/Representation_theory

    Irreducible representations are the building blocks of representation theory for many groups: if a representation is not irreducible then it is built from a subrepresentation and a quotient that are both "simpler" in some sense; for instance, if is finite-dimensional, then both the subrepresentation and the quotient have smaller dimension ...

  9. Dihedral group of order 6 - Wikipedia

    en.wikipedia.org/wiki/Dihedral_group_of_order_6

    Up to isomorphism, this group has three irreducible complex unitary representations, which we will call (the trivial representation), and , where the subscript indicates the dimension. By its definition as a permutation group over the set with three elements, the group has a representation on C 3 {\displaystyle \mathbb {C} ^{3}} by permuting ...