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Stoichiometric names are the simplest and reflect either the empirical formula or the molecular formula. The ordering of the elements follows the formal electronegativity list for binary compounds and electronegativity list to group the elements into two classes which are then alphabetically sequenced. The proportions are specified by di-, tri ...
The rule has also been extended to predict bond lengths in Grimm–Sommerfeld compounds. When the sum of the atomic numbers is the same the bond lengths are the same. [ 4 ] An example is the series of bond lengths ranging from 244.7 pm to 246 pm. for the Ge–Ge bond in elemental germanium , the Ga–As bond in gallium arsenide , the Zn–Se ...
Hydrates are ionic compounds that have absorbed water. They are named as the ionic compound followed by a numerical prefix and -hydrate. The numerical prefixes used are listed below (see IUPAC numerical multiplier): mono-di-tri-tetra-penta-hexa-hepta-octa-nona-deca-For example, CuSO 4 ·5H 2 O is "copper(II) sulfate pentahydrate".
For type-I ionic binary compounds, the cation (a metal in most cases) is named first, and the anion (usually a nonmetal) is named second. The cation retains its elemental name (e.g., iron or zinc), but the suffix of the nonmetal changes to -ide. For example, the compound LiBr is made of Li + cations and Br − anions; thus, it is called lithium ...
A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.
Binary hydrogen compounds in group 1 are the ionic hydrides (also called saline hydrides) wherein hydrogen is bound electrostatically. Because hydrogen is located somewhat centrally in an electronegative sense, it is necessary for the counterion to be exceptionally electropositive for the hydride to possibly be accurately described as truly behaving ionic.
Fundamentally, the Hume-Rothery rules are restricted to binary systems that form either substitutional or interstitial solid solutions. However, this approach limits assessing advanced alloys which are commonly multicomponent systems. Free energy diagrams (or phase diagrams) offer in-depth knowledge of equilibrium restraints in complex systems.
The 18-electron rule is a chemical rule of thumb used primarily for predicting and rationalizing formulas for stable transition metal complexes, especially organometallic compounds. [1] The rule is based on the fact that the valence orbitals in the electron configuration of transition metals consist of five ( n −1)d orbitals, one n s orbital ...