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Triplet oxygen, 3 O 2, refers to the S = 1 electronic ground state of molecular oxygen (dioxygen). Molecules of triplet oxygen contain two unpaired electrons, making triplet oxygen an unusual example of a stable and commonly encountered diradical : [ 2 ] it is more stable as a triplet than a singlet .
The energy difference of 94.3 kJ/mol between ground state and singlet oxygen corresponds to a forbidden singlet-triplet transition in the near-infrared at ~1270 nm. [12] As a consequence, singlet oxygen in the gas phase is relatively long lived (54-86 milliseconds), [ 13 ] although interaction with solvents reduces the lifetime to microseconds ...
Triatomic oxygen (ozone, O 3) is a very reactive allotrope of oxygen that is a pale blue gas at standard temperature and pressure. Liquid and solid O 3 have a deeper blue color than ordinary O 2, and they are unstable and explosive. [5] [6] In its gas phase, ozone is destructive to materials like rubber and fabric and is damaging to lung tissue ...
Different types of pumps are suitable for different applications, for example: a pump's maximum lift height also determines the applications it can be used for. Low-lift pumps are only suitable for the pumping of surface water (e.g., irrigation, drainage of lands, ...), while high-lift pumps allow deep water pumping (e.g., potable water pumping ...
Diradicals are usually triplets.The phrases singlet and triplet are derived from the multiplicity of states of diradicals in electron spin resonance: a singlet diradical has one state (S=0, M s =2*0+1=1, m s =0) and exhibits no signal in EPR and a triplet diradical has 3 states (S=1, M s =2*1+1=3, m s =-1; 0; 1) and shows in EPR 2 peaks (if no hyperfine splitting).
In chemistry and biology, reactive oxygen species (ROS) are highly reactive chemicals formed from diatomic oxygen (O 2), water, and hydrogen peroxide. Some prominent ROS are hydroperoxide (H 2 O 2), superoxide (O 2 −), [1] hydroxyl radical (OH.), and singlet oxygen(1 O 2). [2] ROS are pervasive because they are readily produced from O 2 ...
While some bottled water is from a spring or filtration system, research shows that nearly 65% of bottled water sold in the U.S. comes from municipal tap water. But Rumpler says there can be ...
The triplet-singlet transition is also "forbidden". This presents an additional barrier to the reaction. It also means molecular oxygen is relatively unreactive at room temperature except in the presence of a catalytic heavy atom such as iron or copper. Combustion consists of various radical chain reactions that the singlet radical can initiate.