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The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
The elementary charge, usually denoted by e, is a fundamental physical constant, defined as the electric charge carried by a single proton (+1 e) or, equivalently, the magnitude of the negative electric charge carried by a single electron, which has charge −1 e.
Electrons have an electric charge of −1.602 176 634 × 10 −19 coulombs, [80] which is used as a standard unit of charge for subatomic particles, and is also called the elementary charge. Within the limits of experimental accuracy, the electron charge is identical to the charge of a proton, but with the opposite sign. [83]
Electric charge is a conserved property: the net charge of an isolated system, the quantity of positive charge minus the amount of negative charge, cannot change. Electric charge is carried by subatomic particles. In ordinary matter, negative charge is carried by electrons, and positive charge is carried by the protons in the nuclei of atoms ...
In modern terms, the idea is that electrons move many times faster than atoms, so the electrons are always in equilibrium when atoms move (the Born–Oppenheimer approximation). With this approximation, each asperity contact during sliding is equivalent to a stationary one; there is no direct coupling between the sliding velocity and electron ...
The coulomb was originally defined, using the latter definition of the ampere, as 1 A × 1 s. [4] The 2019 redefinition of the ampere and other SI base units fixed the numerical value of the elementary charge when expressed in coulombs and therefore fixed the value of the coulomb when expressed as a multiple of the fundamental charge.
The electrons that are closest to the nucleus will 'see' nearly all of them. However, electrons further away are screened from the nucleus by other electrons in between, and feel less electrostatic interaction as a result. The 1s electron of iron (the closest one to the nucleus) sees an effective atomic number (number of protons) of 25. The ...