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Acrolein (systematic name: propenal) is the simplest unsaturated aldehyde. It is a colorless liquid with a foul and acrid aroma. It is a colorless liquid with a foul and acrid aroma. The smell of burnt fat (as when cooking oil is heated to its smoke point ) is caused by glycerol in the burning fat breaking down into acrolein.
Besides, 3-hydroxypropionaldehyde suffers an spontaneous dehydration in aqueous solution, and the resulting molecule is called acrolein. [3] In fact, the term reuterin is the name given to the dynamic system formed by 3-hydroxypropionaldehyde, its hydrate, the dimer, and acrolein. This last molecule, acrolein, was recently included in reuterin ...
In organic chemistry, acroleinide is a functional group which is composed of a cyclic ketal of a diol with acrolein. [1] In pharmaceutical chemistry, it is present in acrocinonide (triamcinolone acroleinide). [1]
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Its reaction with acrolein is the first step in the commercial synthesis of glutaraldehyde. The alkene can be deprotonated at the vinyl carbon adjacent to the oxygen. [6] In particular, this approach allows the synthesis of a variety of acyl derivatives of silicon, germanium, and tin that cannot be made easily by other routes. [7] [8] [9]
These two anticancer agents, in vivo, may be converted to urotoxic metabolites, such as acrolein. Mesna assists to detoxify these metabolites by reaction of its sulfhydryl group with α,β-unsaturated carbonyl containing compounds such as acrolein. [5] This reaction is known as a Michael addition. Mesna also increases urinary excretion of cysteine.
The reaction is the basis of several quantitative tests for glycerol. Acrolein and aldehyde condensation products are formed when glycerol vapors are passed over alumina at 360° C. Finely divided copper at 330° C. causes glycerol to decompose to acrolein, ally1 alcohol, ethyl alcohol, hydrogen and small amounts of carbon monoxide.
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