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  2. Free-radical halogenation - Wikipedia

    en.wikipedia.org/wiki/Free-radical_halogenation

    For example, consider radical bromination of toluene: [5] bromination of toluene with hydrobromic acid and hydrogen peroxide in water. This reaction takes place on water instead of an organic solvent and the bromine is obtained from oxidation of hydrobromic acid with hydrogen peroxide. An incandescent light bulb suffices to radicalize.

  3. Halogen addition reaction - Wikipedia

    en.wikipedia.org/wiki/Halogen_addition_reaction

    A halogen addition reaction is a simple organic reaction where a halogen molecule is added to the carbon–carbon double bond of an alkene functional group. [1]The general chemical formula of the halogen addition reaction is:

  4. N-Bromosuccinimide - Wikipedia

    en.wikipedia.org/wiki/N-Bromosuccinimide

    The NBS product precipitates and can be collected by filtration. [2] Crude NBS gives better yield in the Wohl–Ziegler reaction. In other cases, impure NBS (slightly yellow in color) may give unreliable results. It can be purified by recrystallization from 90 to 95 °C water (10 g of NBS for 100 mL of water). [1]

  5. Electrophilic halogenation - Wikipedia

    en.wikipedia.org/wiki/Electrophilic_halogenation

    In organic chemistry, an electrophilic aromatic halogenation is a type of electrophilic aromatic substitution.This organic reaction is typical of aromatic compounds and a very useful method for adding substituents to an aromatic system.

  6. Halogenation - Wikipedia

    en.wikipedia.org/wiki/Halogenation

    Bromination is more selective than chlorination because the reaction is less exothermic. Illustrative of the bromination of an alkene is the route to the anesthetic halothane from trichloroethylene: [6] Iodination and bromination can be effected by the addition of iodine and bromine to alkenes.

  7. Toluene - Wikipedia

    en.wikipedia.org/wiki/Toluene

    Toluene (/ ˈ t ɒ l. j u iː n /), also known as toluol (/ ˈ t ɒ l. j u. ɒ l , - ɔː l , - oʊ l / ), is a substituted aromatic hydrocarbon [ 15 ] with the chemical formula C 6 H 5 CH 3 , often abbreviated as PhCH 3 , where Ph stands for the phenyl group.

  8. Friedel–Crafts reaction - Wikipedia

    en.wikipedia.org/wiki/Friedel–Crafts_reaction

    In commercial applications, the alkylating agents are generally alkenes, some of the largest scale reactions practiced in industry.Such alkylations are of major industrial importance, e.g. for the production of ethylbenzene, the precursor to polystyrene, from benzene and ethylene and for the production of cumene from benzene and propene in cumene process:

  9. Bromine compounds - Wikipedia

    en.wikipedia.org/wiki/Bromine_compounds

    Bromination of metals with Br 2 tends to yield lower oxidation states than chlorination with Cl 2 when a variety of oxidation states is available. Bromides can be made by reaction of an element or its oxide, hydroxide, or carbonate with hydrobromic acid, and then dehydrated by mildly high temperatures combined with either low pressure or ...