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In an alkane, each carbon atom is sp 3-hybridized with 4 sigma bonds (either C–C or C–H), and each hydrogen atom is joined to one of the carbon atoms (in a C–H bond). The longest series of linked carbon atoms in a molecule is known as its carbon skeleton or carbon backbone. The number of carbon atoms may be considered as the size of the ...
Number of C atoms Number of isomers [3] [4] Number of isomers including stereoisomers [3] [5] Molecular Formula Name of straight chain Synonyms 1 1 1 CH 4: methane: methyl hydride; natural gas 2 1 1 C 2 H 6: ethane: dimethyl; ethyl hydride; methyl methane 3 1 1 C 3 H 8: propane: dimethyl methane; propyl hydride 4 2 2 C 4 H 10: n-butane: butyl ...
Norbornane (also called bicyclo[2.2.1]heptane). Unsubstituted cycloalkanes that contain a single ring in their molecular structure are typically named by adding the prefix "cyclo" to the name of the corresponding linear alkane with the same number of carbon atoms in its chain as the cycloalkane has in its ring.
Alkanes from nonane to hexadecane (those alkanes with nine to sixteen carbon atoms) are liquids of higher viscosity, which are less suitable for use in gasoline. They form instead the major part of diesel, kerosene, and aviation fuel. Diesel fuels are characterised by their cetane number, cetane being an older name for hexadecane.
Hydrocarbon prefixes: These prefixes indicate the number of carbon atoms in a straight-chain alkane. Some examples include: meth- (1 carbon) eth- (2 carbons) prop- (3 carbons) but- (4 carbons) pent- (5 carbons) hex- (6 carbons) Alkyl group prefixes: These prefixes are used to name alkyl groups (chains of carbon atoms) that are attached to ...
In the case of chlorination, one of the chlorine atoms replaces a hydrogen atom. The reactions proceed via free-radical pathways, in which the halogen first dissociates into a two neutral radical atoms (homolytic fission). CH 4 + Cl 2 → CH 3 Cl + HCl CH 3 Cl + Cl 2 → CH 2 Cl 2 + HCl. all the way to CCl 4 (carbon tetrachloride) C 2 H 6 + Cl ...
n-, iso- and cyclo-alkanes (saturated hydrocarbons) n-, iso- and cyclo-alkenes and -alkynes (unsaturated hydrocarbons). Important examples of low-molecular aliphatic compounds can be found in the list below (sorted by the number of carbon-atoms):
Thus, the name is 3-methylpentane to avoid ambiguity: The 3- is because the methyl is attached to the third of the five carbon atoms. If there is more than one of the same alkyl group attached to a chain, then the prefixes are used on the alkyl groups to indicate multiples (i.e., di, tri, tetra, etc.)