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[18]: 1165 Examples of this include the octacyanomolybdate (Mo(CN) 4− 8) and octafluorozirconate (ZrF 4− 8) anions. [18]: 1165 The nonahydridorhenate ion (ReH 2− 9) in potassium nonahydridorhenate is a rare example of a compound with a steric number of 9, which has a tricapped trigonal prismatic geometry. [13]: 254 [18]
The Curtin–Hammett principle is a principle in chemical kinetics proposed by David Yarrow Curtin and Louis Plack Hammett.It states that, for a reaction that has a pair of reactive intermediates or reactants that interconvert rapidly (as is usually the case for conformational isomers), each going irreversibly to a different product, the product ratio will depend both on the difference in ...
c) The rate of reaction progress (product formation) is monitored over time by methods such as reaction progress calorimetry or may be obtained by taking the first derivative of (a). d) Describing the rate of reaction progress with respect to consumption of starting material spreads the data into a more informative distribution than observed in ...
A mnemonic is a memory aid used to improve long-term memory and make the process of consolidation easier. Many chemistry aspects, rules, names of compounds, sequences of elements, their reactivity, etc., can be easily and efficiently memorized with the help of mnemonics.
Chemical classification systems attempt to classify elements or compounds according to certain chemical functional or structural properties. Whereas the structural properties are largely intrinsic, functional properties and the derived classifications depend to a certain degree on the type of chemical interaction partners on which the function is exerted.
The following outline acts as an overview of and topical guide to chemistry: . Chemistry is the science of atomic matter (matter that is composed of chemical elements), especially its chemical reactions, but also including its properties, structure, composition, behavior, and changes as they relate to the chemical reactions.
A scientific law is "inferred from particular facts, applicable to a defined group or class of phenomena, and expressible by the statement that a particular phenomenon always occurs if certain conditions be present". [7] The production of a summary description of our environment in the form of such laws is a fundamental aim of science.
For example, a mixture of SO 2 and O 2 is metastable as there is a kinetic barrier to formation of the product, SO 3. 2 SO 2 + O 2 ⇌ 2 SO 3 The barrier can be overcome when a catalyst is also present in the mixture as in the contact process , but the catalyst does not affect the equilibrium concentrations.