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Sodium bisulfite (or sodium bisulphite, sodium hydrogen sulfite) is a chemical mixture with the approximate chemical formula NaHSO 3. Sodium bisulfite is not a real compound, [ 2 ] but a mixture of salts that dissolve in water to give solutions composed of sodium and bisulfite ions.
The bisulfite ion (IUPAC-recommended nomenclature: hydrogensulfite) is the ion HSO − 3. Salts containing the HSO − 3 ion are also known as "sulfite lyes". [1] Sodium bisulfite is used interchangeably with sodium metabisulfite (Na 2 S 2 O 5). Sodium metabisulfite dissolves in water to give a solution of Na + HSO − 3. Na 2 S 2 O 5 + H 2 O ...
Sodium bisulfate, also known as sodium hydrogen sulfate, [a] is the sodium salt of the bisulfate anion, with the molecular formula NaHSO 4. Sodium bisulfate is an acid salt formed by partial neutralization of sulfuric acid by an equivalent of sodium base, typically in the form of either sodium hydroxide (lye) or sodium chloride (table salt).
Similar reactions are effected with divalent cations (Mg2+, Ca2+) and using carbonates in place of hydroxide. The ratio of sulfite to bisulfite depends on pH; above pH=7, sulfite predominates. Calcium-based. The earliest process used calcium, obtained as inexpensive calcium carbonate, and there was little incentive to recover the inorganic ...
The organic reaction also goes by the name Bucherer-Lepetit reaction or (incorrectly) the Bucherer-Le Petit reaction. The reaction is used to convert 1,7-dihydroxynaphthalene into 7-amino-1-naphthol and 1-aminonaphthalene-4-sulfonic acid into 1-hydroxynaphthalene-4-sulfonic acid. It is also useful for transamination reactions of 2 ...
Upon formation of the adduct, a new extended phase is formed in which the gas molecules are incorporated (inserted) as ligands of the copper atoms within the structure. This reaction can also be considered a reaction between a base and a Lewis acid where the copper atom plays the electron-receiving role and the pi electrons of the gas molecule ...
Hydroxysultaine is prepared industrially by the reaction of sodium bisulfite with epichlorohydrin to give the sodium salt (sodium 1-chloro-2-hydroxypropane sulfonate). [1] This is similar to the synthesis of isethionate , which is also used as a 'head-group' in surfactants.
The further reaction of the Schiff reagent with aldehydes is complex with several research groups reporting multiple reaction products with model compounds. In the currently accepted mechanism, the pararosaniline and bisulfite combine to yield the "decolorized" adduct with sulfonation at the central carbon as described and shown.