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Hund's rule of maximum multiplicity is a rule based on observation of atomic spectra, which is used to predict the ground state of an atom or molecule with one or more open electronic shells. The rule states that for a given electron configuration , the lowest energy term is the one with the greatest value of spin multiplicity . [ 1 ]
In atomic physics and quantum chemistry, Hund's rules refers to a set of rules that German physicist Friedrich Hund formulated around 1925, which are used to determine the term symbol that corresponds to the ground state of a multi-electron atom. The first rule is especially important in chemistry, where it is often referred to simply as Hund's ...
Hund's rules should not be used to predict the order of states other than the lowest for a given configuration. (See examples at Hund's rules § Excited states .) If only two equivalent electrons are involved, there is an "Even Rule" which states that, for two equivalent electrons, the only states that are allowed are those for which the sum (L ...
Friedrich Hermann Hund (4 February 1896 – 31 March 1997) was a German physicist from Karlsruhe known for his work on atoms and molecules. [1] He is known for the Hund's rules to predict the electron configuration of chemical elements. His work on Hund's cases and molecular orbital theory allowed to understand the structure of molecules.
Sieverts's law, in physical metallurgy, is a rule to predict the solubility of gases in metals. Named after German chemist Adolf Sieverts (1874–1947). Smeed's law is an empirical rule relating traffic fatalities to traffic congestion as measured by the proxy of motor vehicle registrations and country population. After R. J. Smeed.
An example of Hund's case (c) is the lowest 3 Π u state of diiodine (I 2), which approximates more closely to case (c) than to case (a). [ 6 ] The selection rules for S {\displaystyle S} , Ω {\displaystyle \Omega } and parity are valid as for cases (a) and (b), but there are no rules for Λ {\displaystyle \Lambda } and Σ {\displaystyle ...
Download as PDF; Printable version; In other projects Wikimedia Commons; ... Hudde's rules; Hume-Rothery rules; Hund's rule of maximum multiplicity; Hund's rules; I.
Main-group atoms generally obey the octet rule, while transition metals generally obey the 18-electron rule. The noble gases (He, Ne, Ar, Kr, Xe, Rn) are less reactive than other elements because they already have a noble gas configuration. Oganesson is predicted to be more reactive due to relativistic effects for heavy atoms.