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The compound is a salt consisting of ferrioxalate anions, [Fe(C 2 O 4) 3] 3−, and potassium cations K +. The anion is a transition metal oxalate complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate C 2 O 2− 4 ligands. Potassium is a counterion, balancing the −3 charge of the complex.
Potassium ferrioxalate crystals. Metal oxalate complexes are photoactive, degrading with loss of carbon dioxide. This reaction is the basis of the technique called actinometry. Ferrioxalate undergoes photoreduction.
Ferrioxalate or trisoxalatoferrate(III) is a trivalent anion with formula [Fe(C 2 O 4) 3] 3−.It is a transition metal complex consisting of an iron atom in the +3 oxidation state and three bidentate oxalate ions C 2 O 2− 4 anions acting as ligands.
It is a red-brown paramagnetic solid. It is the potassium salt of tetraperoxochromate(V), one of the few examples of chromium in the +5 oxidation state and one of the rare examples of a complex stabilized only by peroxide ligands. [2] This compound is used as a source of singlet oxygen. [1]
Potassium hypochromate is a chemical compound with the formula K 3 CrO 4 with the unusual Cr 5+ ion. This compound is unstable in water but stable in alkaline solution [ 1 ] and was found to have a similar crystal structure to potassium hypomanganate .
Zeise's salt was one of the first organometallic compounds to be reported. [6] It was discovered by William Christopher Zeise, a professor at the University of Copenhagen, who prepared this compound in 1830 while investigating the reaction of PtCl 4 with boiling ethanol.
Potassium chlorochromate is an inorganic compound with the formula KCrO 3 Cl. [4] It is the potassium salt of chlorochromate, [CrO 3 Cl] −. It is a water-soluble orange compound is used occasionally for oxidation of organic compounds. It is sometimes called Péligot's salt, in recognition of its discoverer Eugène-Melchior Péligot.
The reaction can be demonstrated by starting with solutions of potassium cyanate and ammonium chloride which are mixed, heated and cooled again. An additional proof of the chemical transformation is obtained by adding a solution of oxalic acid which forms urea oxalate as a white precipitate. [3]