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Negative electron affinities can be used in those cases where electron capture requires energy, i.e. when capture can occur only if the impinging electron has a kinetic energy large enough to excite a resonance of the atom-plus-electron system. Conversely electron removal from the anion formed in this way releases energy, which is carried out ...
The energy released when an electron is added to a neutral gaseous atom to form an anion is known as electron affinity. [14] Trend-wise, as one progresses from left to right across a period, the electron affinity will increase as the nuclear charge increases and the atomic size decreases resulting in a more potent force of attraction of the ...
The electron affinity of molecules is a complicated function of their electronic structure. For instance the electron affinity for benzene is negative, as is that of naphthalene, while those of anthracene, phenanthrene and pyrene are positive. In silico experiments show that the electron affinity of hexacyanobenzene surpasses that of fullerene. [5]
The Mulliken electronegativity can only be calculated for an element whose electron affinity is known. Measured values are available for 72 elements, while approximate values have been estimated or calculated for the remaining elements. The Mulliken electronegativity of an atom is sometimes said to be the negative of the chemical potential. [14]
Like its neighbors in the periodic table, tennessine is expected to have the lowest electron affinity—energy released when an electron is added to the atom—in its group; 2.6 or 1.8 eV. [4]
Elements are placed in the periodic table according to their electron configurations, [38] the periodic recurrences of which explain the trends in properties across the periodic table. [ 39 ] An electron can be thought of as inhabiting an atomic orbital , which characterizes the probability it can be found in any particular region around the atom.
See also: Electronegativities of the elements (data page) There are no reliable sources for Pm, Eu and Yb other than the range of 1.1–1.2; see Pauling, Linus (1960).
The construction of the periodic table ignores these irregularities and is based on ideal electron configurations. [2] Note the non-linear shell ordering, which comes about due to the different energies of smaller and larger shells.