Search results
Results From The WOW.Com Content Network
Fluorine's chemistry is dominated by its strong tendency to gain an electron. It is the most electronegative element and elemental fluorine is a strong oxidant. The removal of an electron from a fluorine atom requires so much energy that no known reagents are known to oxidize fluorine to any positive oxidation state. [20]
Fluorine is highly electronegative, resulting in this significant decrease in bond angle. In predicting the bond angle of water, Bent's rule suggests that hybrid orbitals with more s character should be directed towards the lone pairs, while that leaves orbitals with more p character directed towards the hydrogens, resulting in deviation from ...
Fluorine is a chemical element; it has symbol F and atomic number 9. It is the lightest halogen [note 1] and exists at standard conditions as pale yellow diatomic gas. Fluorine is extremely reactive as it reacts with all other elements except for the light inert gases. It is highly toxic.
Pauling estimated that an electronegativity difference of 1.7 (on the Pauling scale) corresponds to 50% ionic character, so that a difference greater than 1.7 corresponds to a bond which is predominantly ionic. [10] Ionic character in covalent bonds can be directly measured for atoms having quadrupolar nuclei (2 H, 14 N, 81,79 Br, 35,37 Cl or ...
Fluorine is an insulator in all of its forms. It has a high ionisation energy (1681 kJ/mol), high electron affinity (328 kJ/mol), and high electronegativity (3.98). Fluorine is a powerful oxidising agent (F 2 + 2e → 2HF = 2.87 V at pH 0); "even water, in the form of steam, will catch fire in an atmosphere of fluorine". [9]
A list of the electron affinities was used by Robert S. Mulliken to develop an electronegativity scale for atoms, equal to the average of the electrons affinity and ionization potential. [ 2 ] [ 3 ] Other theoretical concepts that use electron affinity include electronic chemical potential and chemical hardness .
The high electronegativity of fluorine (4.0 for fluorine vs. 2.5 for carbon) gives the carbon–fluorine bond a significant polarity or dipole moment. The electron density is concentrated around the fluorine, leaving the carbon relatively electron poor. This introduces ionic character to the bond through partial charges (C δ+ —F δ−). The ...
Unlike the other halogens, fluorine atoms have high electronegativity and small size which is able to stabilize them. Chlorine pentafluoride (ClF 5) is a colourless gas, made by reacting chlorine trifluoride with fluorine at high temperatures and high pressures. It reacts violently with water and most metals and nonmetals.