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Altogether, there are 9 different stable water isotopologues, [2] and 9 radioactive isotopologues involving tritium, [3] for a total of 18. However only certain ratios are possible in mixture, due to prevalent hydrogen swapping. The atom(s) of the different isotope may be anywhere in a molecule, so the difference is in the net chemical formula.
Oxygen in Earth's air is 99.759% 16 O, 0.037% 17 O and 0.204% 18 O. [13] Water molecules with a lighter isotope are slightly more likely to evaporate and less likely to fall as precipitation, [14] so Earth's freshwater and polar ice have slightly less (0.1981%) 18 O than air (0.204%) or seawater (0.1995%).
In the case of the hydrogen isotope tritium (half-life = 12.3 years) and carbon-14 (half-life = 5,730 years), these isotopes derive their importance from all organic life containing hydrogen and carbon and therefore can be used to study countless living processes, reactions, and phenomena.
This is a list of radioactive nuclides (sometimes also called isotopes), ordered by half-life from shortest to longest, in seconds, minutes, hours, days and years. Current methods make it difficult to measure half-lives between approximately 10 −19 and 10 −10 seconds.
Deuterium, 2 H (atomic mass 2.014 101 777 844 (15) Da), the other stable hydrogen isotope, has one proton and one neutron in its nucleus, called a deuteron. 2 H comprises 26–184 ppm (by population, not mass) of hydrogen on Earth; the lower number tends to be found in hydrogen gas and higher enrichment (150 ppm) is typical of seawater.
Tritium (from Ancient Greek τρίτος (trítos) 'third') or hydrogen-3 (symbol T or 3 H) is a rare and radioactive isotope of hydrogen with a half-life of ~12.3 years. The tritium nucleus (t, sometimes called a triton) contains one proton and two neutrons, whereas the nucleus of the common isotope hydrogen-1 (protium) contains one proton and no neutrons, and that of non-radioactive hydrogen ...
The labeled molecules or radiopharmaceuticals have to be synthesized after the radiofluorine is prepared, as the high energy proton radiation would destroy the molecules. Large amounts of oxygen-18 enriched water are used in positron emission tomography centers, for on-site production of 18 F-labeled fludeoxyglucose (FDG).
Water molecules carry unique isotopic "fingerprints", based in part on differing ratios of the oxygen and hydrogen isotopes that constitute the water molecule. Isotopes are atoms of the same element that have a different number of neutrons in their nuclei. Air, freshwater and seawater contain mostly oxygen-16 ( 16 O).