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Cyanide is quantified by potentiometric titration, a method widely used in gold mining. It can also be determined by titration with silver ion. Some analyses begin with an air-purge of an acidified boiling solution, sweeping the vapors into a basic absorber solution. The cyanide salt absorbed in the basic solution is then analyzed. [47]
If the acyl groups are different, then they are named in alphabetical order in the same way, with anhydride replacing acid and IUPAC name consists of three words. For example, CH 3 CO−O−OCCH 3 is called ethanoic anhydride and CH 3 CO−O−OCCH 2 CH 3 is called ethanoic propanoic anhydride.
Aldol condensation can occur when acetyl cyanide reacts with (Z)-but-2-enal to form (2E,4E)-hexa-2,4-dienoyl cyanide: The photochemical and thermal reactions of acetyl cyanide have been extensively studied. For example, formyl cyanide does not undergo unimolecular decomposition to HCN and CO spontaneously. However, acetyl cyanide, also a member ...
The word cyanide for the radical in hydrogen cyanide was derived from its French equivalent, cyanure, which Gay-Lussac constructed from the Ancient Greek word κύανος for dark blue enamel or lapis lazuli, again owing to the chemical’s derivation from Prussian blue. Incidentally, the Greek word is also the root of the English color name cyan.
Cyanogen is typically generated from cyanide compounds. One laboratory method entails thermal decomposition of mercuric cyanide: . 2 Hg(CN) 2 → (CN) 2 + Hg 2 (CN) 2 Or, one can combine solutions of copper(II) salts (such as copper(II) sulfate) with cyanides; an unstable copper(II) cyanide is formed which rapidly decomposes into copper(I) cyanide and cyanogen.
Formyl cyanide is a simple organic compound with the formula HCOCN and structure HC(=O)−C≡N. It is simultaneously a nitrile (R−C≡N) and an aldehyde (R−CH=O). Formyl cyanide is the simplest member of the acyl cyanide family. It is known to occur in space in the Sgr B2 molecular cloud. [1]
Sodium cyanide is a compound with the formula Na C N and the structure Na + − C≡N. It is a white, water-soluble solid. Cyanide has a high affinity for metals, which leads to the high toxicity of this salt .
Iron(II) cyanide Names IUPAC name. Iron(II) cyanide. ... cyanide is an inorganic compound with the empirical formula Fe(CN) 2. It may have a Fe 2 [Fe ...