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XPS physics - the photoelectric effect.. Because the energy of an X-ray with particular wavelength is known (for Al K α X-rays, E photon = 1486.7 eV), and because the emitted electrons' kinetic energies are measured, the electron binding energy of each of the emitted electrons can be determined by using the photoelectric effect equation,
Electron spectroscopy refers to a group formed by techniques based on the analysis of the energies of emitted electrons such as photoelectrons and Auger electrons.This group includes X-ray photoelectron spectroscopy (XPS), which also known as Electron Spectroscopy for Chemical Analysis (ESCA), Electron energy loss spectroscopy (EELS), Ultraviolet photoelectron spectroscopy (UPS), and Auger ...
Because binding energy values are more readily applied and understood, the kinetic energy values, which are source dependent, are converted into binding energy values, which are source independent. This is achieved by applying Einstein's relation E k = h ν − E B {\displaystyle E_{k}=h\nu -E_{B}} .
Chart of nuclides (isotopes) by binding energy, depicting the valley of stability. The diagonal line corresponds to equal numbers of neutrons and protons. Dark blue squares represent nuclides with the greatest binding energy, hence they correspond to the most stable nuclides. The binding energy is greatest along the floor of the valley of ...
X-ray absorption near edge structure (XANES), also known as near edge X-ray absorption fine structure (NEXAFS), is a type of absorption spectroscopy that indicates the features in the X-ray absorption spectra of condensed matter due to the photoabsorption cross section for electronic transitions from an atomic core level to final states in the energy region of 50–100 eV above the selected ...
Atoms can be excited by a high-energy beam of charged particles such as electrons (in an electron microscope for example), protons (see PIXE) or a beam of X-rays (see X-ray fluorescence, or XRF or also recently in transmission XRT). These methods enable elements from the entire periodic table to be analysed, with the exception of H, He and Li.
The band structure is thus translated from energies at which the electrons are bound within the material, to energies that free them from the crystal binding and enable their detection outside of the material. By measuring the freed electron's kinetic energy, its velocity and absolute momentum can be calculated.
Energy-dispersive X-ray spectroscopy (EDS, EDX, EDXS or XEDS), sometimes called energy dispersive X-ray analysis (EDXA or EDAX) or energy dispersive X-ray microanalysis (EDXMA), is an analytical technique used for the elemental analysis or chemical characterization of a sample. It relies on an interaction of some source of X-ray excitation and ...