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The equation parameters and all other information required to calculate values of the important thermodynamic functions are stored in a thermodynamic datafile. The values are organized in a format that makes them readable by a thermodynamic calculation program or for use in a spreadsheet.
A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodynamic engine during the conversion of heat into work, or conversely, the efficiency of a refrigeration system in creating a temperature difference through ...
Q H = W + Q C = heat exchanged with the hot reservoir. η = W / (Q C + Q H) = thermal efficiency of the cycle If the cycle moves in a clockwise sense, then it is a heat engine that outputs work; if the cycle moves in a counterclockwise sense, it is a heat pump that takes in work and moves heat Q H from the cold reservoir to the hot reservoir.
The Carnot cycle is a cycle composed of the totally reversible processes of isentropic compression and expansion and isothermal heat addition and rejection. The thermal efficiency of a Carnot cycle depends only on the absolute temperatures of the two reservoirs in which heat transfer takes place, and for a power cycle is:
Carnot's principle was recognized by Carnot at a time when the caloric theory represented the dominant understanding of the nature of heat, before the recognition of the first law of thermodynamics, and before the mathematical expression of the concept of entropy. Interpreted in the light of the first law, Carnot's analysis is physically ...
The word equilibrium implies a state of balance. Equilibrium thermodynamics, in origins, derives from analysis of the Carnot cycle. Here, typically a system, as cylinder of gas, initially in its own state of internal thermodynamic equilibrium, is set out of balance via heat input from a combustion reaction. Then, through a series of steps, as ...
Only one equation of state will not be sufficient to reconstitute the fundamental equation. All equations of state will be needed to fully characterize the thermodynamic system. Note that what is commonly called "the equation of state" is just the "mechanical" equation of state involving the Helmholtz potential and the volume:
Since a Carnot heat engine is a reversible heat engine, and all reversible heat engines operate with the same efficiency between the same reservoirs, we have the first part of Carnot's theorem: No irreversible heat engine is more efficient than a Carnot heat engine operating between the same two thermal reservoirs.