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[6] [7] At least two modern reproductions of Scheele's green hue with modern non-toxic pigments have been made, with similar but non-identical color coordinates: one with hex#3c7a18 (RGB 60, 122, 24) and another with hex#478800 (RGB 71, 136, 0). [8] [9] The latter is the more typically reported color coordinate for Scheele's green. [10]
Emerald Green, also known as Paris Green, Scheele's Green, Schweinfurt green and Vienna Green, is a synthetic inorganic compound, made by a reaction of sodium arsenite with copper(II) acetate. While it makes a beautiful rich green, the color of the emerald stone, it is highly toxic, due to a main ingredient, arsenic. [18]
Sodium arsenite can be inhaled or absorbed through the skin. Along with its known carcinogenic and teratogenic effects, contact with the substance can yield symptoms such as skin irritation, burns, itching, thickened skin, rash, loss of pigment, poor appetite, a metallic or garlic taste, stomach pain, nausea, vomiting, diarrhea, convulsions, decreased blood pressure, and headache.
Copper pigments. Han purple: BaCuSi 2 O 6. Cobalt pigments. Cobalt violet (PV14): Co 3 (PO 4) 2. Manganese pigments. Manganese violet: NH 4 MnP 2 O 7 (PV16) manganic ammonium pyrophosphate. [2] Gold pigments. Purple of Cassius: Gold nanoparticles suspended in tin dioxide - Au x • SnO 2. Arsenic pigments. London purple As 2 O 3. [3]
Arsenate (+5 oxidation state) is the dominant form of arsenic in surface water, while arsenite (+3 oxidation state) is the dominant form in hypoxic to anoxic environments. Arsenite is more soluble and mobile than arsenate. Many species of bacteria can transform arsenite to arsenate in anoxic conditions by using arsenite as an electron donor. [189]
It is a highly toxic emerald-green crystalline powder [4] that has been used as a rodenticide and insecticide, [5] and also as a pigment. It was manufactured in 1814 to be a pigment to make a vibrant green paint, and was used by many notable painters in the 19th century.