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The formation of Fe(III)-EDTA (FeY) − can be described as follows: FeSO 4 ∙7H 2 O + K 2 H 2 Y + 1/4 O 2 → K[FeY(H 2 O)]. H 2 O + KHSO 4 + 5.5 H 2 O (1) [8]. Iron chelate has also been used as a bait in the chemical control of slugs, snails and slaters in agriculture in Australia and New Zealand.
Iron can be made available immediately to the plant by the use of iron sulphate or iron chelate compounds. Two common iron chelates are Fe EDTA and Fe EDDHA. Iron sulphate (Iron(II) sulfate) and iron EDTA are only useful in soil up to PH 7.1 but they can be used as a foliar spray (Foliar feeding). Iron EDDHA is useful up to PH 9 (highly ...
Sprint 138 iron chelate is produced as Na-Fe-EDDHA (C 18 H 16 FeN 2 NaO 6), while Hoagland's original solution formulations contain ferric tartrate (C 12 H 12 Fe 2 O 18), but no sodium ions. [ 1 ] [ 2 ] [ 3 ] Synthesizing a sodium-free ferric EDTA complex (C 10 H 12 FeN 2 O 8 − ) in a laboratory is sometimes preferred to buying ready-made ...
The reduction strategy helps in making the iron more aqueous soluble, and allows the iron to become more bioavailable in order for uptake to occur. This is because the Fe 2+ product is not able to mineralize like the Fe 3+, as it does not bind significantly to the chelate ligand that is designed to bind Fe 3+.
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Treatments with iron(II) sulfate have higher incidence of adverse events than iron(III)-hydroxide polymaltose complex (IPC) [29] [30] [31] or iron bis-glycinate chelate. [32] [33] Iron overdose has been one of the leading causes of death caused by toxicological agents in children younger than six years. [34] Iron poisoning may result in ...