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In organic chemistry, the acetoxy group (abbr. AcO or OAc; IUPAC name: acetyloxy [1]), is a functional group with the formula −OCOCH 3 and the structure −O−C(=O)−CH 3. As the -oxy suffix implies, it differs from the acetyl group (−C(=O)−CH 3) by the presence of an additional oxygen atom. The name acetoxy is the short form of acetyl-oxy.
The technique was introduced in the field of peptide synthesis by Robert Bruce Merrifield in 1977. [111] For peptide synthesis via automated machine, the orthogonality of the Fmoc group (basic cleavage), the tert‑butyl group (acidic cleavage) and diverse protecting groups for functional groups on the amino acid side-chains are used. [112]
Salicylic acid is acetylated to form aspirin. In chemistry, acetylation is an organic esterification reaction with acetic acid.It introduces an acetyl group into a chemical compound.
Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule. The atoms in a functional group are linked to each other and to the rest of the molecule by covalent bonds.
In chemistry, a leaving group is defined by the IUPAC as an atom or group of atoms that detaches from the main or residual part of a substrate during a reaction or elementary step of a reaction. [1] However, in common usage, the term is often limited to a fragment that departs with a pair of electrons in heterolytic bond cleavage . [ 2 ]
In IUPAC nomenclature, an acetyl group is called an ethanoyl group. An acetyl group contains a methyl group ( −CH 3 ) that is single-bonded to a carbonyl ( C=O ), making it an acyl group . The carbonyl center of an acyl radical has one non-bonded electron with which it forms a chemical bond to the remainder (denoted with the letter R ) of the ...
Demethylation is the chemical process resulting in the removal of a methyl group (CH 3) from a molecule. [1] [2] A common way of demethylation is the replacement of a methyl group by a hydrogen atom, resulting in a net loss of one carbon and two hydrogen atoms. The counterpart of demethylation is methylation.
Acetylated wood is a type of modified wood that is produced through a chemical modification process. [1] It produced from a chemical reaction (named as acetylation), involving acetic anhydride and a modification process to make wood highly resistant to biological attacks by fungi and wood-boring insects and durable to environmental conditions.