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Adiabatic ionization is a form of ionization in which an electron is removed from or added to an atom or molecule in its lowest energy state to form an ion in its lowest energy state. [16] The Townsend discharge is a good example of the creation of positive ions and free electrons due to ion impact.
Chemical ionization (CI) is a soft ionization technique used in mass spectrometry. [ 1 ] [ 2 ] This was first introduced by Burnaby Munson and Frank H. Field in 1966. [ 3 ] This technique is a branch of gaseous ion-molecule chemistry. [ 2 ]
A certain amount of energy, which may be large enough, is required to remove an electron from an atom or a molecule in its ground state. [12] [13] In chemi-ionization processes, the energy consumed by the ionization must be stored in atoms or molecules in a form of potencial energy or can be obtained from an accompanying exothermic chemical change (for example, from a formation of a new ...
The DART ionization process can produce positive or negative ions depending on the potential applied to the exit electrode. This ionization can occur for species desorbed directly from surfaces such as bank notes, tablets, bodily fluids (blood, saliva and urine), polymers, glass, plant leaves, fruits & vegetables, clothing, and living organisms.
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
The terms fractional ionization and ionization fraction are also used to describe either the proportion of neutral particles that are ionized or the proportion of free electrons. [ 3 ] [ 4 ] When referred to an atom, "fully ionized" means that there are no bound electrons left, resulting in a bare nucleus .
Ionization energy is positive for neutral atoms, meaning that the ionization is an endothermic process. Roughly speaking, the closer the outermost electrons are to the nucleus of the atom, the higher the atom's ionization energy. In physics, ionization energy (IE) is usually expressed in electronvolts (eV) or joules (J).
Electron capture ionization (ECI) is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A −•.The reaction is + where the M over the arrow denotes that to conserve energy and momentum a third body is required (the molecularity of the reaction is three).