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Pyridine crystallizes in an orthorhombic crystal system with space group Pna2 1 and lattice parameters a = 1752 pm, b = 897 pm, c = 1135 pm, and 16 formula units per unit cell (measured at 153 K). For comparison, crystalline benzene is also orthorhombic, with space group Pbca , a = 729.2 pm, b = 947.1 pm, c = 674.2 pm (at 78 K), but the number ...
The Hückel method or Hückel molecular orbital theory, proposed by Erich Hückel in 1930, is a simple method for calculating molecular orbitals as linear combinations of atomic orbitals. The theory predicts the molecular orbitals for π-electrons in π-delocalized molecules , such as ethylene , benzene , butadiene , and pyridine .
4-Dimethylaminopyridine (DMAP) is a derivative of pyridine with the chemical formula (CH 3) 2 NC 5 H 4 N. This white solid is of interest because it is more basic than pyridine, owing to the resonance stabilisation from the NMe 2 substituent.
Transition metal pyridine complexes encompass many coordination complexes that contain pyridine as a ligand. Most examples are mixed-ligand complexes. Most examples are mixed-ligand complexes. Many variants of pyridine are also known to coordinate to metal ions, such as the methylpyridines, quinolines, and more complex rings.
Pyridine-N-oxide is the heterocyclic compound with the formula C 5 H 5 NO. This colourless, hygroscopic solid is the product of the oxidation of pyridine . It was originally prepared using peroxyacids as the oxidising agent.
3-methyl pyridine is biodegradable, although it degrades more slowly and volatilize more readily from water samples than either 2-methyl- or 4-methyl-pyridine., [7] [8] 3-Methylpyridine is the main precursor to niacin , one of the B vitamins .
It is the conjugate acid of pyridine. Many related cations are known involving substituted pyridines, e.g. picolines, lutidines, collidines. They are prepared by treating pyridine with acids. [3] As pyridine is often used as an organic base in chemical reactions, pyridinium salts are produced in many acid-base reactions.
Oxidation of quinoline affords quinolinic acid (pyridine-2,3-dicarboxylic acid), a precursor to the herbicide sold under the name "Assert". [8] The reduction of quinoline with sodium borohydride in the presence of acetic acid is known to produce Kairoline A. [15] (C.f. Kairine) Several anti-malarial drugs contain quinoline substituents.