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Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. [1] [2] It is an important type of alkaline hydrolysis. When the carboxylate is long chain, its salt is called a soap. The saponification of ethyl acetate gives sodium acetate ...
Example of saponification reaction of a triglyceride molecule (left) with potassium hydroxide (KOH) yielding glycerol (purple) and salts of fatty acids ().. Saponification value or saponification number (SV or SN) represents the number of milligrams of potassium hydroxide (KOH) or sodium hydroxide (NaOH) required to saponify one gram of fat under the conditions specified.
Sodium hydroxide, also known as lye and caustic soda, [1] [2] is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na + and hydroxide anions OH −. Sodium hydroxide is a highly corrosive base and alkali that decomposes lipids and proteins at ambient temperatures and may cause severe ...
Alkaline hydrolysis of esters is also known as saponification. A base such as sodium hydroxide is required in stochiometric amounts. Unlike acid-catalyzed ester hydrolysis, it is not an equilibrium reaction and proceeds to completion. Hydroxide ion attacks the carbonyl carbon to give a tetrahedral intermediate, which then expels an alkoxide ion.
The production of toilet soaps usually entails saponification of triglycerides, which are vegetable or animal oils and fats. An alkaline solution (often lye or sodium hydroxide) induces saponification whereby the triglyceride fats first hydrolyze into salts of fatty acids. Glycerol (glycerin) is liberated. The glycerin is sometimes left in the ...
Pellets of soda lye (sodium hydroxide) Pellets of potash lye (potassium hydroxide)Lye is a hydroxide, either sodium hydroxide or potassium hydroxide.The word lye most accurately refers to sodium hydroxide (NaOH), [citation needed] but historically has been conflated to include other alkali materials, most notably potassium hydroxide (KOH).
(The hydroxide solution used in such a titration is typically made from sodium hydroxide, potassium hydroxide, or barium hydroxide.) [1] It is measure of the steam volatile and water insoluble fatty acids, chiefly caprylic, capric and lauric acids, present in oil and fat. The value is named for the chemist who developed it, Eduard Polenske.
Through the process of saponification, fats (like tallow, pig, and bone fats) or vegetable oils react with sodium hydroxide to form the sodium salts of fatty acids and glycerin. [1] The resulting mixture is known as soft soap [broken anchor], which serves as a precursor for hard soap production.