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A smaller amount of chloromethane is produced by treating a mixture of methane with chlorine at elevated temperatures. This method, however, also produces more highly chlorinated compounds such as dichloromethane, chloroform, and carbon tetrachloride. For this reason, methane chlorination is usually only practiced when these other products are ...
Several billion kilograms of chlorinated methanes are produced annually, mainly by chlorination of methane: CH 4 + x Cl 2 → CH 4−x Cl x + x HCl. The most important is dichloromethane, which is mainly used as a solvent. Chloromethane is a precursor to chlorosilanes and silicones.
The production of the anesthetic 2-bromo-2-chloro-1,1,1-trifluoroethane ... chlorine and hydrogen based on methane and ethane has been examined and most have been ...
A radical abstracts a hydrogen atom from methane, leaving a primary methyl radical. The methyl radical then abstracts Cl • from Cl 2 to give the desired product and another chlorine radical. Methane chlorination: propagation The radical will then participate in another propagation reaction: the radical chain. Other products such as CH 2 Cl 2 ...
A third major source is marine algae, which produce several chlorinated methane and ethane containing compounds. Several thousand complex halocarbons are known to be produced mainly by marine species. Although chlorine compounds are the majority of the discovered compounds, bromides, iodides and fluorides have also been found in nature.
DCM is produced by treating either chloromethane or methane with chlorine gas at 400–500 °C. At these temperatures, both methane and chloromethane undergo a series of reactions producing progressively more chlorinated products. In this way, an estimated 400,000 tons were produced in the US, Europe, and Japan in 1993. [12] CH 4 + Cl 2 → CH ...
Methane is also subjected to free-radical chlorination in the production of chloromethanes, although methanol is a more typical precursor. [35] Hydrogen can also be produced via the direct decomposition of methane, also known as methane pyrolysis, which, unlike steam reforming, produces no greenhouse gases (GHG). The heat needed for the ...
The commercial production of chlorinated paraffins for use as high-pressure additives in lubricants began around 1930. [6] Around 1935 the process was technically stable and commercially successful. [5] However, it was only in the years after World War II that a greater build-up of photochloration capacity began.