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Manganese(II,III) oxide is the chemical compound with formula Mn 3 O 4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO · Mn 2 O 3 . Mn 3 O 4 is found in nature as the mineral hausmannite .
A particularly common oxidation state for manganese in aqueous solution is +2, which has a pale pink color. Many manganese(II) compounds are known, such as the aquo complexes derived from manganese(II) sulfate (MnSO 4) and manganese(II) chloride (MnCl 2). This oxidation state is also seen in the mineral rhodochrosite (manganese(II) carbonate ...
Manganese(II) oxide is an inorganic compound with chemical formula MnO. [2] It forms green crystals. The compound is produced on a large scale as a component of fertilizers and food additives .
The oxygen-evolving complex is the site of water oxidation. It is a metallo-oxo cluster comprising four manganese ions (in oxidation states ranging from +3 to +4) [6] and one divalent calcium ion. When it oxidizes water, producing oxygen gas and protons, it sequentially delivers the four electrons from water to a tyrosine (D1-Y161) sidechain ...
In a classical laboratory demonstration, heating a mixture of potassium chlorate and manganese dioxide produces oxygen gas. Manganese dioxide also catalyses the decomposition of hydrogen peroxide to oxygen and water: 2 H 2 O 2 → 2 H 2 O + O 2. Manganese dioxide decomposes above about 530 °C to manganese(III) oxide and oxygen.
Manganese can form compounds in the +2, +3 and +4 oxidation states. The manganese(II) compounds are often light pink solids. Like some other metal difluorides, MnF 2 crystallizes in the rutile structure, which features octahedral Mn centers. [29] and it is used in the manufacture of special kinds of glass and lasers. [30]
Photons trapped by photosystem II move the system from state S 0 to S 1 to S 2 to S 3 and finally to S 4. S 4 reacts with water producing free oxygen: 2 H 2 O → O 2 + 4 H + + 4 e −. This conversion resets the catalyst to the S 0 state. The active site of the OEC consists of a cluster of manganese and calcium with the formula Mn 4 Ca 1 O x ...
[5] γ-Mn 2 O 3 can be produced by oxidation followed by dehydration of manganese(II) hydroxide. [5] Many preparations of nano-crystalline Mn 2 O 3 have been reported, for example syntheses involving oxidation of Mn II salts or reduction of MnO 2. [6] [7] [8] Manganese(III) oxide is formed by the redox reaction in an alkaline cell: