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3′-Phosphoadenosine-5′-phosphosulfate (PAPS) is a derivative of adenosine monophosphate (AMP) that is phosphorylated at the 3′ position and has a sulfate group attached to the 5′ phosphate. It is the most common coenzyme in sulfotransferase reactions and hence part of sulfation pathways . [ 1 ]
Bifunctional 3'-phosphoadenosine 5'-phosphosulfate synthetase 1 is an enzyme that in humans is encoded by the PAPSS1 gene. [5] [6] [7]Three-prime-phosphoadenosine 5-prime-phosphosulfate is the sulfate donor cosubstrate for all sulfotransferase (SULT) enzymes (Xu et al., 2000).
73836 Ensembl ENSG00000157593 ENSMUSG00000037089 UniProt Q8TB61 Q91ZN5 RefSeq (mRNA) NM_178148 NM_001286509 NM_001286510 NM_001286511 NM_001286512 NM_001286513 NM_001286517 NM_001286519 NM_001286520 NM_028662 NM_001357105 RefSeq (protein) NP_001273438 NP_001273439 NP_001273440 NP_001273441 NP_001273442 NP_001273446 NP_001273448 NP_001273449 NP_835361 NP_001344034 Location (UCSC) Chr 6: 44.25 ...
Bifunctional 3'-phosphoadenosine 5'-phosphosulfate synthetase 2 is an enzyme that in humans is encoded by the PAPSS2 gene. [5] [6]Sulfation is a common modification of endogenous (lipids, proteins, and carbohydrates) and exogenous (xenobiotics and drugs) compounds.
Adenosine 3',5'-bisphosphate is produced as a product of sulfotransferase enzymes from the donation of a sulfate group from the coenzyme 3'-phosphoadenosine-5'-phosphosulfate. [ 1 ] [ 2 ] This product is then hydrolysed by 3'(2'),5'-bisphosphate nucleotidase to give adenosine monophosphate , which can then be recycled into adenosine triphosphate .
In eukaryotic cells the activated sulfate donor is 3'-phosphoadenosine-5'-phosphosulfate (PAPS) (Figure 1). [5] Figure 1: A general carbohydrate sulfotransferase reaction. PAPS is shown as the activated sulfate donor; PAPS is the sulfate donor in eukaryotic cells.
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In biochemistry, sulfotransferases (SULTs) are transferase enzymes that catalyze the transfer of a sulfo group (R−SO − 3) from a donor molecule to an acceptor alcohol (R−OH) or amine (R−NH 2). [1] The most common sulfo group donor is 3'-phosphoadenosine-5'-phosphosulfate (PAPS). In the case of alcohol as acceptor, the product is a ...