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Arsenic forms colorless, odorless, crystalline oxides As 2 O 3 ("white arsenic") and As 2 O 5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and the salts are called arsenates , [ 5 ] the most common arsenic contamination of groundwater , and a problem that affects many people.
Diamond and graphite are two allotropes of carbon: pure forms of the same element that differ in crystalline structure.. Allotropy or allotropism (from Ancient Greek ἄλλος (allos) ' other ' and τρόπος (tropos) ' manner, form ') is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements.
Other reactions of main group compounds with yellow arsenic have been shown to involve units of arsenic with more than four atoms. In reaction with the silylene compound [PhC(NtBu) 2 SiN(SiMe 3) 2], an aggregation of As 4 was observed to form a cage compound of ten arsenic atoms, including a seven-membered arsenic ring at its center. [9]
One of the simplest arsenic compounds is the trihydride, the highly toxic, flammable, pyrophoric arsine (AsH 3). This compound is generally regarded as stable, since at room temperature it decomposes only slowly. At temperatures of 250–300 °C decomposition to arsenic and hydrogen is rapid. [34]
The following table gives the crystalline structure of the most thermodynamically stable form(s) for elements that are solid at standard temperature and pressure. Each element is shaded by a color representing its respective Bravais lattice, except that all orthorhombic lattices are grouped together.
[16] [17] [18] A molecule may be homonuclear, that is, it consists of atoms of one chemical element, as with two atoms in the oxygen molecule (O 2); or it may be heteronuclear, a chemical compound composed of more than one element, as with water (two hydrogen atoms and one oxygen atom; H 2 O). A molecule is the smallest unit of a substance that ...
In chemistry, an arsenide is a compound of arsenic with a less electronegative element or elements. Many metals form binary compounds containing arsenic, and these are called arsenides. They exist with many stoichiometries, and in this respect arsenides are similar to phosphides. [1]
These compounds have structures similar to the phosphorus sulfides. Arsenic-arsenic bonds are very weak, and oligomeric arsenic compounds are even more liable to oxidize than their hydrogenated precursors. [6]: 318–320 The following reaction can, however, be prepared through electrochemical reduction in a zinc-sulfate cell.