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The McMurry reaction of benzophenone. The McMurry reaction is an organic reaction in which two ketone or aldehyde groups are coupled to form an alkene using a titanium chloride compound such as titanium(III) chloride and a reducing agent. The reaction is named after its co-discoverer, John E. McMurry.
In addition to his scientific work, McMurry is the author of 45 undergraduate chemistry textbooks that have been translated into 12 languages and used throughout the world. McMurry's most popular textbook Organic Chemistry was first printed in 1984. In 2022, he sold the rights for the book to OpenStax making it free for the user.
McMurry3rd is for referencing the 3rd edition (1992) of Organic Chemistry by John E. McMurry. It is based on the template {}. Parameters are: page (optional): to reference a single page; pages (optional): to reference multiple pages
Phenol is an organic compound appreciably soluble in water, with about 84.2 g dissolving in 1000 ml (0.895 M). Homogeneous mixtures of phenol and water at phenol to water mass ratios of ~2.6 and higher are possible. The sodium salt of phenol, sodium phenoxide, is far more water-soluble. It is a combustible solid (NFPA rating = 2).
Elias James Corey (born July 12, 1928) is an American organic chemist.In 1990, he won the Nobel Prize in Chemistry "for his development of the theory and methodology of organic synthesis", [3] specifically retrosynthetic analysis.
An aldol condensation is a condensation reaction in organic chemistry in which two carbonyl moieties (of aldehydes or ketones) react to form a β-hydroxyaldehyde or β-hydroxyketone (an aldol reaction), and this is then followed by dehydration to give a conjugated enone. The overall reaction equation is as follows (where the Rs can be H)
In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. [1] Often a substituent moves from one atom to another atom in the same molecule, hence these reactions are usually intramolecular. In the example below ...
In organic chemistry, an electrocyclic reaction is a type of pericyclic, rearrangement reaction where the net result is one pi bond being converted into one sigma bond or vice versa. [1] These reactions are usually categorized by the following criteria: Reactions can be either photochemical or thermal.