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Hydrogen bromide is the inorganic compound with the formula HBr. It is a hydrogen halide consisting of hydrogen and bromine. A colorless gas, it dissolves in water, forming hydrobromic acid , which is saturated at 68.85% HBr by weight at room temperature.
The classic case is sodium bromide, which fully dissociates in water: NaBr → Na + + Br −. Hydrogen bromide, which is a diatomic molecule, takes on salt-like properties upon contact with water to give an ionic solution called hydrobromic acid. The process is often described simplistically as involving formation of the hydronium salt of bromide:
The same is true when an alkene reacts with water in an additional reaction to form an alcohol that involves carbocation formation. The hydroxyl group (OH) bonds to the carbon that has the greater number of carbon-carbon bonds, while the hydrogen bonds to the carbon on the other end of the double bond, that has more carbon–hydrogen bonds.
[3]: 692–694 Hydrogen bromide is incredibly selective as a reagent, [3]: 687–688 and does not produce detectable quantities of polymeric byproducts. [5]: 156–157 The behavior of hydrogen bromide generalizes in two separate directions. Halogenated compounds with a relatively stable radical can dissociate from the halogen.
These methods work best when the bromide product is stable to hydrolysis; otherwise, the possibilities include high-temperature oxidative bromination of the element with bromine or hydrogen bromide, high-temperature bromination of a metal oxide or other halide by bromine, a volatile metal bromide, carbon tetrabromide, or an organic bromide.
Common absorption refrigerators use a refrigerant with a very low boiling point (less than −18 °C (0 °F)) just like compressor refrigerators.Compression refrigerators typically use an HCFC or HFC, while absorption refrigerators typically use ammonia or water and need at least a second fluid able to absorb the coolant, the absorbent, respectively water (for ammonia) or brine (for water).
Hydrobromic acid is an aqueous solution of hydrogen bromide.It is a strong acid formed by dissolving the diatomic molecule hydrogen bromide (HBr) in water. "Constant boiling" hydrobromic acid is an aqueous solution that distills at 124.3 °C (255.7 °F) and contains 47.6% HBr by mass, which is 8.77 mol/L. Hydrobromic acid is one of the strongest mineral acids known.
A hydrogen–bromine battery is a rechargeable flow battery in which hydrogen bromide (HBr) serves as the system’s electrolyte.During the charge cycle, as power flows into the stack, H 2 is generated and stored in a separate tank, the other product of the chemical reaction is HBr 3 which accumulates in the electrolyte.