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For holes, is the number of holes per unit volume in the valence band. To calculate this number for electrons, we start with the idea that the total density of conduction-band electrons, , is just adding up the conduction electron density across the different energies in the band, from the bottom of the band to the top of the band .
Combining the equation for capacitance with the above equation for the energy stored in a capacitor, for a flat-plate capacitor the energy stored is: = =. where is the energy, in joules; is the capacitance, in farads; and is the voltage, in volts.
In this equation, is the number of free charges per unit volume. These charges are the ones that have made the volume non-neutral, and they are sometimes referred to as the space charge . This equation says, in effect, that the flux lines of D must begin and end on the free charges.
The definition of capacitance (C) is the charge (Q) stored per unit voltage (V).= Elastance (S) is the reciprocal of capacitance, thus, [1]= . Expressing the values of capacitors as elastance is not commonly done by practical electrical engineers, but can be convenient for capacitors in series since their total elastance is simply the sum of their individual elastances.
Since the area of the plates increases with the square of the linear dimensions and the separation increases linearly, the capacitance scales with the linear dimension of a capacitor (), or as the cube root of the volume. A parallel plate capacitor can only store a finite amount of energy before dielectric breakdown occurs.
Therefore, as the capacitor charges or discharges, the voltage changes at a different rate than the galvani potential difference. In these situations, one cannot calculate capacitance merely by looking at the overall geometry and using Gauss's law. One must also take into account the band-filling / band-emptying effect, related to the density ...
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where: is the rate of change of the energy density in the volume. ∇•S is the energy flow out of the volume, given by the divergence of the Poynting vector S. J•E is the rate at which the fields do work on charges in the volume (J is the current density corresponding to the motion of charge, E is the electric field, and • is the dot product).