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High-temperature electrolysis schema. Decarbonization of Economy via hydrogen produced from HTE. High-temperature electrolysis (also HTE or steam electrolysis, or HTSE) is a technology for producing hydrogen from water at high temperatures or other products, such as iron or carbon nanomaterials, as higher energy lowers needed electricity to split molecules and opens up new, potentially better ...
Solid oxide electrolyzer cells operate at temperatures which allow high-temperature electrolysis [5] to occur, typically between 500 and 850 °C. These operating temperatures are similar to those conditions for a solid oxide fuel cell. The net cell reaction yields hydrogen and oxygen gases.
High temperature (950–1000 °C) gas cooled nuclear reactors have the potential to split hydrogen from water by thermochemical means using nuclear heat. High-temperature electrolysis has been demonstrated in a laboratory, at 108 MJ (thermal) per kilogram of hydrogen produced, [150] but not at a commercial scale. In addition, this is lower ...
Whereas the common PEM fuel cell, also called Low Temperature Proton Exchange Membrane fuel cell (LT-PEM), must usually be operated with hydrogen with high purity of more than 99.9 % the HT-PEM fuel cell is less sensitive to impurities and thus is typically operated with reformate gas with hydrogen concentration of about 50 to 75 %.
Solid oxide fuel cell operates at high temperatures with high fuel-to-electricity conversion ratios and it is a good candidate for high temperature electrolysis. [7] Less electricity is required for electrolysis process in solid oxide regenerative fuel cells (SORFC) due to high temperature.
Usually, the electricity consumed is more valuable than the hydrogen produced, so this method has not been widely used. In contrast with low-temperature electrolysis, high-temperature electrolysis (HTE) of water converts more of the initial heat energy into chemical energy (hydrogen), potentially doubling efficiency to about 50%.
Alternatively, phase-change materials characterized by high fusion points can be used to store heat at high temperature and enable the endothermic operation in the electrolysis mode. In this case, usually, rSOCs operate at different temperature levels in the two modalities (for example, 850°C in SOFC mode and 800°C in SOEC mode). [12]
Further studies are needed to see if the water is potable.Places that are dry and have water shortages could use the water for agriculture or other greywater uses. [7] [8] Another use would be to use the hot water by-product for High-temperature electrolysis for more hydrogen fuel.