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Typically, the quantum Boltzmann equation is given as only the “collision term” of the full Boltzmann equation, giving the change of the momentum distribution of a locally homogeneous gas, but not the drift and diffusion in space. It was originally formulated by L.W. Nordheim (1928), [3] and by and E. A. Uehling and George Uhlenbeck (1933). [4]
In physics, a homogeneous material or system has the same properties at every point; it is uniform without irregularities. [ 1 ] [ 2 ] A uniform electric field (which has the same strength and the same direction at each point) would be compatible with homogeneity (all points experience the same physics).
The IUPAC definition of a solid solution is a "solid in which components are compatible and form a unique phase". [3]The definition "crystal containing a second constituent which fits into and is distributed in the lattice of the host crystal" given in refs., [4] [5] is not general and, thus, is not recommended.
A Markov process is called a reversible Markov process or reversible Markov chain if there exists a positive stationary distribution π that satisfies the detailed balance equations [13] =, where P ij is the Markov transition probability from state i to state j, i.e. P ij = P(X t = j | X t − 1 = i), and π i and π j are the equilibrium probabilities of being in states i and j, respectively ...
In a chemical reaction, chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. [1] This state results when the forward reaction proceeds at the same rate as the reverse ...
A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another.
In the history of thermodynamics, "On the Equilibrium of Heterogeneous Substances" is a 300-page paper written by American chemical physicist Willard Gibbs. It is one of the founding papers in thermodynamics , along with German physicist Hermann von Helmholtz 's 1882 paper " Thermodynamik chemischer Vorgänge ."
A linear differential equation is homogeneous if it is a homogeneous linear equation in the unknown function and its derivatives. It follows that, if φ(x) is a solution, so is cφ(x), for any (non-zero) constant c. In order for this condition to hold, each nonzero term of the linear differential equation must depend on the unknown function or ...