Search results
Results From The WOW.Com Content Network
For a fully oriented molecule, the dipolar coupling for an 1 H-15 N amide group would be over 20 kHz, and a pair of protons separated by 5 Å would have up to ~1 kHz coupling. However the degree of alignment achieved by applying magnetic field is so low that the largest 1 H-15 N or 1 H-13 C dipolar couplings are <5 Hz. [19]
Magnetic dipole–dipole interaction, also called dipolar coupling, refers to the direct interaction between two magnetic dipoles. Roughly speaking, the magnetic field of a dipole goes as the inverse cube of the distance, and the force of its magnetic field on another dipole goes as the first derivative of the magnetic field. It follows that ...
However, long-range orientation information can be obtained through residual dipolar coupling experiments in a medium which imposes a weak alignment on the nucleic acid molecules. [1] [2] Recently, solid-state NMR methodology has been introduced for the structure determination of nucleic acids. [6]
It's the point at which the soil cannot sustain any additional load without undergoing continuous deformation, in a manner similar to the behaviour of fluids. Certain properties of the soil, like porosity, shear strength, and volume, reach characteristic values. These properties are intrinsic to the type of soil and its initial conditions. [1]
The "feet" of the lineshape correspond to the situation when the principal axis of the coupling interaction is parallel to the magnetic field which is much less statistically relevant. Pake was the first to describe this lineshape and used it to extract the proton-proton distance from his experiments on a single crystal and powdered hydrates of ...
In nuclear chemistry and nuclear physics, J-couplings (also called spin-spin coupling or indirect dipole–dipole coupling) are mediated through chemical bonds connecting two spins. It is an indirect interaction between two nuclear spins that arises from hyperfine interactions between the nuclei and local electrons. [ 1 ]
Soil deposits are affected by the mechanism of transport and deposition to their location. Soils that are not transported are called residual soils—they exist at the same location as the rock from which they were generated. Decomposed granite is a common example of a residual soil. The common mechanisms of transport are the actions of gravity ...
The residual strength occurs for some soils where the shape of the particles that make up the soil become aligned during shearing (forming a slickenside), resulting in reduced resistance to continued shearing (further strain softening). This is particularly true for most clays that comprise plate-like minerals, but is also observed in some ...