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Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X 2 /X − couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V).
A traditional method for the manufacture of KBr is the reaction of potassium carbonate with an iron(III, II) bromide, Fe 3 Br 8, made by treating scrap iron under water with excess bromine: [4] 4 K 2 CO 3 + Fe 3 Br 8 → 8 KBr + Fe 3 O 4 + 4 CO 2
Industrially, it is mainly produced by the reaction of hydrogen gas with bromine gas at 200–400 °C with a platinum catalyst. However, reduction of bromine with red phosphorus is a more practical way to produce hydrogen bromide in the laboratory: [2] 2 P + 6 H 2 O + 3 Br 2 → 6 HBr + 2 H 3 PO 3 H 3 PO 3 + H 2 O + Br 2 → 2 HBr + H 3 PO 4
Sodium bromide can be used as a source of the chemical element bromine. This can be accomplished by treating an aqueous solution of NaBr with chlorine gas: 2 NaBr + Cl 2 → Br 2 + 2 NaCl
A bromide ion is the negatively charged form (Br −) of the element bromine, a member of the halogens group on the periodic table.Most bromides are colorless. Bromides have many practical roles, being found in anticonvulsants, flame-retardant materials, and cell stains. [3]
The high-bromine brines in the Appalachian Basin are found in Silurian and Devonian rocks, in Pennsylvania, Ohio, and West Virginia. The principal source of the brine in Ohio and West Virginia was the Pottsville Formation, also called the Big Salt Sand. In Pennsylvania, bromine brine was pumped from the Pocono Sandstone. [2]
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