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It is also used as a precipitating water softener, which combines with hard water minerals (calcium- and magnesium-based minerals) to form an insoluble precipitate, removing these hardness minerals from the water. [5] It is the carbonate moiety which forms the precipitate, the bicarbonate being included to moderate the material's alkalinity.
It gave rise to derivative products which have diverged from the original composition. Today, Calgon water softener contains the active ingredient sodium citrate, [2] and the now discontinued powder used zeolite and polycarboxylate, all of which are less problematic in wastewater treatment than phosphates.
Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions. Soft water also extends the lifetime of plumbing by reducing or eliminating scale build-up in pipes
Additionally, magnesium can be precipitated as magnesium hydroxide in a double displacement reaction. [3] In the process both the calcium (and to an extent magnesium) in the raw water as well as the calcium added with the lime are precipitated. This is in contrast to ion exchange softening where sodium is exchanged for calcium and magnesium ions.
Dishwasher salt is a particular grade of granulated, crystalline sodium chloride intended for regenerating the water softener circuit of household or industrial dishwashers. Analogous to water softener salt, dishwasher salt regenerates ion exchange resins, expelling the therein trapped calcium and magnesium ions that characterize hard water.
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In the 1960s scientists recognized that phosphates in water caused eutrophication. [23] There was disagreement at that time about whether water with high phosphate came to have the chemical because of somehow being polluted with it. [23] By the 1970s it was established that high phosphate levels in water were a consequence of pollution. [23]