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In chemistry, metamerism is used to define the isomeric relationship between compounds with the same polyvalent, heteroatomic, functional group but differ in the main carbon chain or any of the side chains. It has rather been an obsolete term for isomerism, which has not been recognised by IUPAC in its publications. [1]
In organic chemistry, ethers are a class of compounds that contain an ether group—a single oxygen atom bonded to two separate carbon atoms, each part of an organyl group (e.g., alkyl or aryl). They have the general formula R−O−R′ , where R and R′ represent the organyl groups.
Ethyl group (highlighted blue) as part of a molecule, as the ethyl radical, and in the compounds ethanol, bromoethane, ethyl acetate, and ethyl methyl ether.. In organic chemistry, an ethyl group (abbr. Et) is an alkyl substituent with the formula −CH 2 CH 3, derived from ethane (C 2 H 6).
For example, butanol H 3 C−(CH 2) 3 −OH, methyl propyl ether H 3 C−(CH 2) 2 −O−CH 3, and diethyl ether (H 3 CCH 2 −) 2 O have the same molecular formula C 4 H 10 O but are three distinct structural isomers. The concept applies also to polyatomic ions with the same total charge. A classical example is the cyanate ion O=C=N − and ...
In organic chemistry, the Smiles rearrangement is an organic reaction and a rearrangement reaction named after British chemist Samuel Smiles. [1] [2] It is an intramolecular, nucleophilic aromatic substitution of the type: Smiles rearrangement
Ether cleavage refers to chemical substitution reactions that lead to the cleavage of ethers. Due to the high chemical stability of ethers, the cleavage of the C-O bond is uncommon in the absence of specialized reagents or under extreme conditions. [1] [2] In organic chemistry, ether cleavage is an acid catalyzed nucleophilic substitution reaction.
The following outline is provided as an overview of and topical guide to organic chemistry: . Organic chemistry is the scientific study of the structure, properties, composition, reactions, and preparation (by synthesis or by other means) of carbon-based compounds, hydrocarbons, and their derivatives.
The Williamson ether synthesis is an organic reaction, forming an ether from an organohalide and a deprotonated alcohol . This reaction was developed by Alexander Williamson in 1850. [ 2 ] Typically it involves the reaction of an alkoxide ion with a primary alkyl halide via an S N 2 reaction .