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In chemistry, many reactions depend on the absorption of photons to provide the energy needed to overcome the activation energy barrier and hence can be labelled light-dependent. Such reactions range from the silver halide reactions used in photographic film to the creation and destruction of ozone in the upper atmosphere .
Photoexcitation is the first step in a photochemical process where the reactant is elevated to a state of higher energy, an excited state.The first law of photochemistry, known as the Grotthuss–Draper law (for chemists Theodor Grotthuss and John W. Draper), states that light must be absorbed by a chemical substance in order for a photochemical reaction to take place.
Redox reactions are chemical reactions in which electrons are transferred from a donor molecule to an acceptor molecule. The underlying force driving these reactions is the Gibbs free energy of the reactants relative to the products. If donor and acceptor (the reactants) are of higher free energy than the reaction products, the electron ...
Photosensitization is a process of transferring the energy of absorbed light. After absorption, the energy is transferred to the (chosen) reactants. This is part of the work of photochemistry in general. In particular this process is commonly employed where reactions require light sources of certain wavelengths that are not readily available. [14]
Noncyclic photophosphorylation through light-dependent reactions of photosynthesis at the thylakoid membrane. Photosynthesis is the process in which light energy is absorbed and converted to chemical energy. This chemical energy is eventually used in the conversion of carbon dioxide to sugar in plants.
Reactants of the photoreactions can be both gaseous and liquids. [11] In general, it is necessary to bring the reactants close to the light source in order to obtain the highest possible luminous efficacy. For this purpose, the reaction mixture can be irradiated either directly or in a flow-through side arm of a reactor with a suitable light ...
Such reactions require the addition of energy in the form of heat or light. A typical example of a unimolecular reaction is the cis–trans isomerization, in which the cis-form of a compound converts to the trans-form or vice versa. [15] In a typical dissociation reaction, a bond in a molecule splits (ruptures) resulting in two molecular fragments.
Unlike most chemical reactions, the product C converts to a further product, which is produced in an electronically excited state often indicated with an asterisk: A + B → C C → D* D* then emits a photon (hν), to give the ground state of D: [1] I D* → D + hν. In theory, one photon of light should be given off for each molecule of reactant.