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VSEPR theory is used to predict the arrangement of electron pairs around central atoms in molecules, especially simple and symmetric molecules. A central atom is defined in this theory as an atom which is bonded to two or more other atoms, while a terminal atom is bonded to only one other atom.
The geometry is common for certain main group compounds that have a stereochemically-active lone pair, as described by VSEPR theory. Certain compounds crystallize in both the trigonal bipyramidal and the square pyramidal structures, notably [Ni(CN) 5] 3−. [1]
Ryutaro Tsuchida (槌田·龍太郎; 1903-1962) [1] was a Japanese chemist. [2]Tsuchida graduated from Tokyo University in (昭和3年，Shōwa era 3rd) 1928. [1] In June 1935, he established a fifth course at Osaka University. [3]
In VSEPR theory the electron pairs on the oxygen atom in water form the vertices of a tetrahedron with the lone pairs on two of the four vertices. The H–O–H bond angle is 104.5°, less than the 109° predicted for a tetrahedral angle, and this can be explained by a repulsive interaction between the lone pairs. [2] [3] [4]
Representative d-orbital splitting diagrams for square planar complexes featuring σ-donor (left) and σ+π-donor (right) ligands. A general d-orbital splitting diagram for square planar (D 4h) transition metal complexes can be derived from the general octahedral (O h) splitting diagram, in which the d z 2 and the d x 2 −y 2 orbitals are degenerate and higher in energy than the degenerate ...
According to VSEPR theory, diethyl ether, methanol, water and oxygen difluoride should all have a bond angle of 109.5 o. [12] Using VSEPR theory, all these molecules should have the same bond angle because they have the same "bent" shape. [12] Yet, clearly the bond angles between all these molecules deviate from their ideal geometries in ...
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The geometry at xenon is square planar, consistent with VSEPR theory for four ligands and two lone pairs (or AX 4 E 2 in the notation of VSEPR theory). In addition, the existence of an XeO 2 molecule was predicted by an ab initio quantum chemistry method several years earlier by Pyykkö and Tamm, but these authors did not consider an extended ...