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It is now suggested that this reaction proceeds through the intermediate mixed anhydride, resulting from attack by the nucleophilic carboxylate anion on the phosphorus atom, with expulsion of the azide ion. The latter then attacks the carbonyl carbon atom, to give the acyl azide and loss of the diphenylphosphate anion, known to be a good ...
The acyl azide is usually made from the reaction of acid chlorides or anhydrides [6] with sodium azide [7] or trimethylsilyl azide. [8] Acyl azides are also obtained from treating acylhydrazines with nitrous acid. [9] Alternatively, the acyl azide can be formed by the direct reaction of a carboxylic acid with diphenylphosphoryl azide (DPPA ...
The azide functional group can be shown by two resonance structures. An organic azide is an organic compound that contains an azide (– N 3) functional group. [1] Because of the hazards associated with their use, few azides are used commercially although they exhibit interesting reactivity for researchers.
Phenyl azide is an organic compound with the formula C 6 H 5 N 3. It is one of the prototypical organic azides. It is a pale yellow oily liquid with a pungent odor. The structure consists of a linear azide substituent bound to a phenyl group. The C−N=N angle is approximately 116°.
Diphenyl phosphite is a diorganophosphite with the formula (C 6 H 5 O) 2 P(O)H. The molecule is tetrahedral. It is a colorless viscous liquid. The compounds can be prepared by treating phosphorus trichloride with phenol. Many analogues can be prepared similarly.
General ester of phosphonic acid; in fact, the phosphorus has a formal charge of +1, the oxygen above it has a formal charge of −1, and the bond between them is single. In organic chemistry , phosphonates or phosphonic acids are organophosphorus compounds containing C−PO(OR) 2 groups , where R is an organic group ( alkyl , aryl ).
Bisphenol A diphenyl phosphate is a halogen-free flame retardant used plastics. It is used in polymer blends of engineering plastics, such as PPO/HIPS and PC/ABS, [1] which are commonly used to make casing for electrical items like TVs, computers and home appliances. It is formed by the transesterification of bisphenol A with triphenyl phosphate.
Hydrogen bonding from ammonium ion to oxygen atoms causes a change to the difluorophosphate ion in the ammonium salt. [11]On heating the salts that are not of alkali metals or alkaline earth metals, difluorophosphates decompose firstly by giving off POF 3 forming a monofluorophosphate (PO 3 F 2−) compound, and then this in turn decomposes to an orthophosphate PO 3− 4 compound.