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In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.
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Positive deviations (above the mean) and negative deviations (below the mean) are included in the calculation. The mean signed deviation provides a measure of the average distance and direction of data points from the mean, offering insights into the overall trend and distribution of the data. [3]
The negative hypergeometric distribution, a distribution which describes the number of attempts needed to get the nth success in a series of Yes/No experiments without replacement. The Poisson binomial distribution, which describes the number of successes in a series of independent Yes/No experiments with different success probabilities.
The false positive rate (FPR) is the proportion of all negatives that still yield positive test outcomes, i.e., the conditional probability of a positive test result given an event that was not present. The false positive rate is equal to the significance level. The specificity of the test is equal to 1 minus the false positive rate.
In statistics, deviance is a goodness-of-fit statistic for a statistical model; it is often used for statistical hypothesis testing.It is a generalization of the idea of using the sum of squares of residuals (SSR) in ordinary least squares to cases where model-fitting is achieved by maximum likelihood.
Deviations from a straight line suggest departures from normality. The plotting can be manually performed by using a special graph paper, called normal probability paper. With modern computers normal plots are commonly made with software. The normal probability plot is a special case of the Q–Q probability plot for a normal distribution.