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Specific materials and their applications include polymer-protein and polymer-drug conjugates, mediation of enzyme activity, molecular recognition processes and polymeric micelles which can deliver a drug to a specific site in the body. [19] RAFT has also been used to graft polymer chains onto polymeric surfaces, for example, polymeric ...
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks.
Polymer chemistry is a sub-discipline of chemistry that focuses on the structures, chemical synthesis, and chemical and physical properties of polymers and macromolecules. The principles and methods used within polymer chemistry are also applicable through a wide range of other chemistry sub-disciplines like organic chemistry , analytical ...
Polymer nomenclature is generally based upon the type of monomer residues comprising the polymer. A polymer which contains only a single type of repeat unit is known as a homopolymer, while a polymer containing two or more types of repeat units is known as a copolymer. [22] A terpolymer is a copolymer which contains three types of repeat units ...
Enzymatic polymerization is a potential area in polymer research, providing a sustainable and adaptable alternative to conventional polymerization processes. Its capacity to manufacture polymers with exact structures in mild circumstances opens up new possibilities for material design and application, helping to progress both research and industry.
By synthesizing and polymerizing monomers with functionality greater than 2, the 2-D networks instead of linear polymers can be obtained. [28] [4+4] and [4+2] involving anthracene units are popular choices for 2D-polymer synthesis. 2-D covalent networks with high crystallinity can be produced in this way in high conversion.
This work provided the foundations for the synthesis of polymers with improved control over molecular weight, molecular weight distribution, and the architecture. [7] The use of alkali metals to initiate polymerization of 1,3-dienes led to the discovery by Stavely and co-workers at Firestone Tire and Rubber company of cis-1,4-polyisoprene. [8]
Therefore, to terminate the polymerization, a quenching agent must be added, such as a strong acid to protonate the polymer, or a nucleophile to add an end cap the polymer. If the π-complex is too weakly bound, termination of polymer chains can occur before a quenching agent is added, causing lower molecular weight polymers to form.