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The hydrogen cycle consists of hydrogen exchanges between biotic (living) and abiotic (non-living) sources and sinks of hydrogen-containing compounds. Hydrogen (H) is the most abundant element in the universe. [1] On Earth, common H-containing inorganic molecules include water (H 2 O), hydrogen gas (H 2), hydrogen sulfide (H 2 S), and ammonia ...
Paul Sabatier (1854-1941) winner of the Nobel Prize in Chemistry in 1912 and discoverer of the reaction in 1897. The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa [1]) in the presence of a nickel catalyst.
Steam reforming or steam methane reforming (SMR) is a method for producing syngas (hydrogen and carbon monoxide) by reaction of hydrocarbons with water. Commonly natural gas is the feedstock. The main purpose of this technology is often hydrogen production , although syngas has multiple other uses such as production of ammonia or methanol .
Water is the medium of the oceans, the medium which carries all the substances and elements involved in the marine biogeochemical cycles. Water as found in nature almost always includes dissolved substances, so water has been described as the "universal solvent" for its ability to dissolve so many substances.
Methods to produce hydrogen without the use of fossil fuels involve the process of water splitting, or splitting the water molecule (H 2 O) into its components oxygen and hydrogen. When the source of energy for water splitting is renewable or low-carbon, the hydrogen produced is sometimes referred to as green hydrogen .
The sulfur–iodine cycle (S–I cycle) is a series of thermochemical processes used to produce hydrogen. The S–I cycle consists of three chemical reactions whose net reactant is water and whose net products are hydrogen and oxygen. All other chemicals are recycled. The S–I process requires an efficient source of heat.
The methanation reactions are classified as exothermic and their energy of formations are listed. [1] There is disagreement on whether the CO 2 methanation occurs by first associatively adsorbing an adatom hydrogen and forming oxygen intermediates before hydrogenation or dissociating and forming a carbonyl before being hydrogenated. [3]
This occurs because ice (solid water) is less dense than liquid water, as shown by the fact that ice floats on water. At a molecular level, ice is less dense because it has a more extensive network of hydrogen bonding which requires a greater separation of water molecules. [6] Other exceptions include antimony and bismuth. [8] [9]