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A polyolefin is a type of polymer with the general formula (CH 2 CHR) n where R is an alkyl group. They are usually derived from a small set of simple olefins ( alkenes ). Dominant in a commercial sense are polyethylene and polypropylene .
One of the principal methods for alkene synthesis in the laboratory is the elimination reaction of alkyl halides, alcohols, and similar compounds. Most common is the β-elimination via the E2 or E1 mechanism. [ 26 ]
Formation of a secondary alcohol via alkene reduction and hydration is shown: The hydroboration-oxidation and oxymercuration-reduction of alkenes are more reliable in organic synthesis. Alkenes react with N-bromosuccinimide and water in halohydrin formation reaction. Amines can be converted to diazonium salts, which are then hydrolyzed.
In organic chemistry, terminal alkenes (alpha-olefins, α-olefins, or 1-alkenes) are a family of organic compounds which are alkenes (also known as olefins) with a chemical formula C x H 2x, distinguished by having a double bond at the primary, alpha (α), or 1-position. [1]
Sugar alcohols are added to foods because of their lower caloric content than sugars; however, they are also, in general, less sweet, and are often combined with high-intensity sweeteners. They are also added to chewing gum because they are not broken down by bacteria in the mouth or metabolized to acids, and thus do not contribute to tooth decay.
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Straight-chain terminal alkenes, also called linear alpha olefins (LAO) or normal alpha olefins (NAO), are alkenes (olefins) having a chemical formula C n H 2n, distinguished from other alkenes with a similar molecular formula by being terminal alkenes, in which the double bond occurs at the alpha (α-, 1-or primary) position, and by having a linear (unbranched) hydrocarbon chain.
A Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, is a catalyst used in the synthesis of polymers of 1-alkenes (alpha-olefins).Two broad classes of Ziegler–Natta catalysts are employed, distinguished by their solubility: