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Lee [4] developed a modified form of the Antoine equation that allows for calculating vapor pressure across the entire temperature range using the acentric factor (𝜔) of a substance. The fundamental structure of the equation is based on the van der Waals equation and builds upon the findings of Wall [ 5 ] and Gutmann et al. [ 6 ] , who ...
It is typically a number between 0 and 2, rounded to five decimal places which, when multiplied by the observed volume of a liquid, will return a "corrected" value standardized to a base temperature (usually 60 °Fahrenheit or 15 °Celsius).
b is the molality of the solution. A formula to compute the ebullioscopic constant is: [2] = R is the ideal gas constant. M is the molar mass of the solvent. T b is boiling point of the pure solvent in kelvin.
Fahrenheit proposed his temperature scale in 1724, basing it on two reference points of temperature. In his initial scale (which is not the final Fahrenheit scale), the zero point was determined by placing the thermometer in "a mixture of ice , water, and salis Armoniaci [ note 1 ] [transl. ammonium chloride ] or even sea salt". [ 11 ]
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...
The above formula reduces precision at high concentrations, due to nonideality of the solution. If the solute is volatile, one of the key assumptions used in deriving the formula is not true because the equation derived is for solutions of non-volatile solutes in a volatile solvent.
The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).