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Using his extensive measurements of the properties of gases, [6] [7] Mendeleev also calculated it with high precision, within 0.3% of its modern value. [8] The gas constant occurs in the ideal gas law: = = where P is the absolute pressure, V is the volume of gas, n is the amount of substance, m is the mass, and T is the thermodynamic temperature.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
The ideal quantum Boltzmann gas overcomes this limitation by taking the limit of the quantum Bose gas and quantum Fermi gas in the limit of high temperature to specify these additive constants. The behavior of a quantum Boltzmann gas is the same as that of a classical ideal gas except for the specification of these constants.
R = gas constant; N = number of molecules; k = Boltzmann constant = = = = Pressure of an ideal gas ... (for diatomic ideal gas) Internal Energy
However, the ideal gas law is a good approximation for most gases under moderate pressure and temperature. This law has the following important consequences: If temperature and pressure are kept constant, then the volume of the gas is directly proportional to the number of molecules of gas. If the temperature and volume remain constant, then ...
Some constants, such as the ideal gas constant, R, do not describe the state of a system, and so are not properties. On the other hand, some constants, such as K f (the freezing point depression constant, or cryoscopic constant ), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore ...
where R is the ideal gas constant, T is temperature, M is average molecular weight, and g 0 is the gravitational acceleration at the planet's surface. Using the values T=273 K and M=29 g/mol as characteristic of the Earth's atmosphere, H = RT/Mg = (8.315*273)/(29*9.8) = 7.99, or about 8 km, which coincidentally is approximate height of Mt. Everest.
Macroscopically, the ideal gas law states that, for an ideal gas, the product of pressure p and volume V is proportional to the product of amount of substance n and absolute temperature T: =, where R is the molar gas constant (8.314 462 618 153 24 J⋅K −1 ⋅mol −1). [4]