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Osmosis – Migration of molecules to a region of lower solute concentration; Permeation – Penetration of a liquid, gas, or vapor through a solid; Relativistic heat conduction – Model compatible with special relativity; Transport phenomena – Exchange of mass, energy, and momentum between observed and studied systems; Turbulent diffusion
Schematic drawing of a molecule in a cylindrical pore in the case of Knudsen diffusion; are indicated the pore diameter (d) and the free path of the particle (l).Knudsen diffusion, named after Martin Knudsen, is a means of diffusion that occurs when the scale length of a system is comparable to or smaller than the mean free path of the particles involved.
However, for aqueous solutions, the Henry's law solubility constant for many species goes through a minimum. For most permanent gases, the minimum is below 120 °C. Often, the smaller the gas molecule (and the lower the gas solubility in water), the lower the temperature of the maximum of the Henry's law constant.
A molecule in the gas phase is free to rotate relative to a set of mutually orthogonal axes of fixed orientation in space, centered on the center of mass of the molecule. . Free rotation is not possible for molecules in liquid or solid phases due to the presence of intermolecular fo
In spectroscopy, collision-induced absorption and emission refers to spectral features generated by inelastic collisions of molecules in a gas. Such inelastic collisions (along with the absorption or emission of photons) may induce quantum transitions in the molecules, or the molecules may form transient supramolecular complexes with spectral features different from the underlying molecules.
Solubility is the property of a gas, liquid or solid substance (the solute) to be held homogeneously dispersed as molecules or ions in a liquid or solid medium (the solvent). In decompression theory, the solubility of gases in liquids is of primary importance, as it is the formation of bubbles from these gases that causes decompression sickness.
How much gas is present could be specified by giving the mass instead of the chemical amount of gas. Therefore, an alternative form of the ideal gas law may be useful. The chemical amount, n (in moles), is equal to total mass of the gas (m) (in kilograms) divided by the molar mass, M (in kilograms per mole): =.
The absorption of gases in liquids depends on the solubility of the specific gas in the specific liquid, the concentration of gas, customarily measured by partial pressure, and temperature. [1] In the study of decompression theory the behaviour of gases dissolved in the tissues is investigated and modeled for variations of pressure over time. [7]