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The only binary heptafluorides are iodine heptafluoride (IF 7), rhenium heptafluoride (ReF 7), and gold heptafluoride (AuF 7).Only IF 7 and ReF 7 are true heptafluorides, however, as AuF 7 is actually a coordination complex of gold pentafluoride (AuF 5) and molecular fluorine; therefore, the correct chemical formula of gold heptafluoride is actually AuF 5 ·F 2.
The well-characterized heavier halogens (chlorine, bromine, and iodine) all form mono-, tri-, and pentafluorides: XF, XF 3, and XF 5. Of the neutral +7 species, only iodine heptafluoride is known. [93] While chlorine and bromine heptafluorides are not known, the corresponding cations ClF + 6 and BrF + 6, extremely strong oxidizers, are. [94]
All combinations of fluorine, chlorine, bromine, and iodine that have the above-mentioned general formula are known, but not all are stable. Some combinations of astatine with other halogens are not even known, and those that are known are highly unstable. Chlorine monofluoride (ClF) is the lightest interhalogen compound.
The pentagonal bipyramidal iodine heptafluoride (IF 7) is an extremely powerful fluorinating agent, behind only chlorine trifluoride, chlorine pentafluoride, and bromine pentafluoride among the interhalogens: it reacts with almost all the elements even at low temperatures, fluorinates Pyrex glass to form iodine(VII) oxyfluoride (IOF 5), and ...
Bromine fluoride may refer to several compounds with the elements bromine and fluorine: Bromine monofluoride, BrF; Bromine trifluoride, BrF 3; Bromine pentafluoride ...
Iodine heptafluoride is an interhalogen compound with the chemical formula I F 7. [2] [3] It has an unusual pentagonal bipyramidal structure, with D 5h symmetry, as predicted by VSEPR theory. [4] The molecule can undergo a pseudorotational rearrangement called the Bartell mechanism, which is like the Berry mechanism but for a heptacoordinated ...
Bromine pentafluoride, Br F 5, is an interhalogen compound and a fluoride of bromine.It is a strong fluorinating agent.. BrF 5 finds use in oxygen isotope analysis. Laser ablation of solid silicates in the presence of BrF 5 releases O 2 for subsequent analysis. [2]
Bromine monofluoride is a quite unstable interhalogen compound with the chemical formula BrF. It can be produced through the reaction of bromine trifluoride (or bromine pentafluoride) and bromine. Due to its lability, the compound can be detected but not isolated: [2] BrF 3 + Br 2 → 3 BrF BrF 5 + 2 Br 2 → 5 BrF Br 2(l) + F 2(g) → 2 BrF (g)