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The gaps between the bands define the infrared window in the Earth's atmosphere. [17] The infrared spectrum of liquid water is dominated by the intense absorption due to the fundamental O-H stretching vibrations. Because of the high intensity, very short path lengths, usually less than 50 μm, are needed to record the spectra of aqueous solutions.
Diagram showing displacement of the Sun's image at sunrise and sunset Comparison of inferior and superior mirages due to differing air refractive indices, n. Atmospheric refraction is the deviation of light or other electromagnetic wave from a straight line as it passes through the atmosphere due to the variation in air density as a function of height. [1]
Refraction of light is the most commonly observed phenomenon, but other waves such as sound waves and water waves also experience refraction. How much a wave is refracted is determined by the change in wave speed and the initial direction of wave propagation relative to the direction of change in speed.
For example, scattering from clear skies reflects about 32 W/m 2 (about 13%) of incoming solar radiation back to space. [8] Visible light is also reflected and scattered by aerosol particles and water droplets (clouds). Neither of these phenomena have a significant impact on the flux of thermal infrared through clear skies.
Dispersion occurs when sinusoidal waves of different wavelengths have different propagation velocities, so that a wave packet of mixed wavelengths tends to spread out in space. The speed of a plane wave, v {\displaystyle v} , is a function of the wave's wavelength λ {\displaystyle \lambda } :
The effect of frequency dispersion is that the waves travel as a function of wavelength, so that spatial and temporal phase properties of the propagating wave are constantly changing. For example, under the action of gravity, water waves with a longer wavelength travel faster than those with a shorter wavelength.
where v is the speed of the wave (c in a vacuum or less in other media), f is the frequency and λ is the wavelength. As waves cross boundaries between different media, their speeds change but their frequencies remain constant. Electromagnetic waves in free space must be solutions of Maxwell's electromagnetic wave equation. Two main classes of ...
The phase velocity of a wave is the rate at which the wave propagates in any medium. This is the velocity at which the phase of any one frequency component of the wave travels. For such a component, any given phase of the wave (for example, the crest) will appear to travel at the phase velocity.