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4-Pyrone (γ-pyrone or pyran-4-one) is an unsaturated cyclic chemical compound with the molecular formula C 5 H 4 O 2.It is isomeric with 2-pyrone. Preparation [ edit ]
2-Pyrone 4-Pyrone. Pyrones or pyranones are a class of heterocyclic chemical compounds. They contain an unsaturated six-membered lactone ring, which has one oxygen atom and an adjacent ketone functional group. [1] There are two isomers denoted as 2-pyrone and 4-pyrone.
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Likewise a 4-hydroxyl pyrylium compound is a γ-pyrone or pyran-4-one (4), to which group belong compounds such as maltol. pyrones. 2-Pyrones are known to react with alkynes in a Diels–Alder reaction to form arene compounds with expulsion of carbon dioxide, for example: [17] Pyrone cycloaddition
4-Pyridone exists a keto-enol tautomerism with its enol tautomer 4-hydroxypyridine. In solution, the keto tautomer is favoured, [4] and the enol tautomer only becomes important in very dilute solutions or solutions of non-polar solvents. However, the enol tautomer is dominant in the gas phase. [5]
2-Pyrone (α-pyrone or pyran-2-one) is an unsaturated cyclic chemical compound with the molecular formula C 5 H 4 O 2.It is isomeric with 4-pyrone.. 2-Pyrone is used in organic synthesis as a building block for more complex chemical structures because it may participate in a variety of cycloaddition reactions to form bicyclic lactones.
The reaction shown below involves an alkyne oxymercuration reaction to generate the requisite ketone. [10] Early investigation into the Nazarov cyclization. Research involving the reaction was relatively quiet in subsequent years, until in the mid-1980s when several syntheses employing the Nazarov cyclization were published.
The Buchner–Curtius–Schlotterbeck reaction is the reaction of aldehydes or ketones with aliphatic diazoalkanes to form homologated ketones. [1] It was first described by Eduard Buchner and Theodor Curtius in 1885 [ 2 ] and later by Fritz Schlotterbeck in 1907. [ 3 ]