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Watt's indicator diagram. The PV diagram, then called an indicator diagram, was developed in 1796 by James Watt and his employee John Southern. [2] Volume was traced by a plate moving with the piston, while pressure was traced by a pressure gauge whose indicator moved at right angles to the piston.
For a fixed mass of an ideal gas kept at a fixed temperature, pressure and volume are inversely proportional. [2] Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant.
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
Otto cycle pressure–volume diagramThe idealized diagrams of a four-stroke Otto cycle Both diagrams: the intake (0-1 and colored green) stroke is performed by an isobaric expansion, followed by an adiabatic compression (1-2 and colored orange) stroke.
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
Figure 1: Idealized pressure–volume diagram featuring cardiac cycle components. Real-time left ventricular (LV) pressure–volume loops provide a framework for understanding cardiac mechanics in experimental animals and humans.
All four diagrams are derived from the physical P–alpha diagram which combines pressure (P) and specific volume (alpha) as its basic coordinates. The P–alpha diagram shows a strong deformation of the grid for atmospheric conditions and is therefore not useful in atmospheric sciences. The three diagrams are constructed from the P–alpha ...
Because the net variation in state properties during a thermodynamic cycle is zero, it forms a closed loop on a P-V diagram. A P-V diagram's abscissa, Y axis, shows pressure (P) and ordinate, X axis, shows volume (V). The area enclosed by the loop is the net work done by the processes, i.e. the cycle: